Visible-Light Induction/Brønsted Acid Catalysis in Relay for the Enantioselective Synthesis of Tetrahydroquinolines

2019 ◽  
Vol 21 (11) ◽  
pp. 4173-4176 ◽  
Author(s):  
Wenhui Xiong ◽  
Shan Li ◽  
Bo Fu ◽  
Jinping Wang ◽  
Qiu-An Wang ◽  
...  
Author(s):  
Yongbiao Guo ◽  
Zhenhua Gao ◽  
Junchen Li ◽  
Xiaojing Bi ◽  
Enxue Shi ◽  
...  

An efficient, practical and scalable protocol to prepare chiral 2,3-dihydroquinazolinones was developed under catalysis of spirocyclic SPINOL-phosphoric acid.


2020 ◽  
Vol 56 (42) ◽  
pp. 5661-5664
Author(s):  
Yukihiro Arakawa ◽  
Tomohiro Mihara ◽  
Hiroki Fujii ◽  
Keiji Minagawa ◽  
Yasushi Imada

Visible light irradiation to flavins in the presence of thiols and O2 provides Brønsted acidic species that can be used as efficient catalysts for thioacetalizations and for Mannich-type reactions under non-irradiation and mild conditions.


2021 ◽  
Author(s):  
Xiang Wu ◽  
Du Ding ◽  
Ying Zhang ◽  
Hua-Jie Jiang ◽  
Tao Wang ◽  
...  

We describe a catalytic asymmetric iminium ion cyclization reaction of simple 2-alkenylbenzaldimines using a BINOL-derived chiral N-triflyl phosphoramide. The corresponding 1-aminoindenes and tetracyclic 1-aminoindanes are formed in good yields and...


2021 ◽  
Author(s):  
Andrew David Smith ◽  
Feng Zhao ◽  
Chang Shu ◽  
Claire M. Young ◽  
Cameron Carpenter-Warren ◽  
...  

Author(s):  
Alexander Gak ◽  
Svetlana Kuznetsova ◽  
Yulia Nelyubina ◽  
Alexander A. Korlyukov ◽  
Han Li ◽  
...  

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