scholarly journals Brønsted Acid Catalysis in Visible-Light-Induced [2+2] Photocycloaddition Reactions of Enone Dithianes

2017 ◽  
Vol 56 (15) ◽  
pp. 4337-4341 ◽  
Author(s):  
Christoph Brenninger ◽  
Alexander Pöthig ◽  
Thorsten Bach
2020 ◽  
Vol 56 (42) ◽  
pp. 5661-5664
Author(s):  
Yukihiro Arakawa ◽  
Tomohiro Mihara ◽  
Hiroki Fujii ◽  
Keiji Minagawa ◽  
Yasushi Imada

Visible light irradiation to flavins in the presence of thiols and O2 provides Brønsted acidic species that can be used as efficient catalysts for thioacetalizations and for Mannich-type reactions under non-irradiation and mild conditions.


2019 ◽  
Vol 21 (11) ◽  
pp. 4173-4176 ◽  
Author(s):  
Wenhui Xiong ◽  
Shan Li ◽  
Bo Fu ◽  
Jinping Wang ◽  
Qiu-An Wang ◽  
...  

Author(s):  
Yongbiao Guo ◽  
Zhenhua Gao ◽  
Junchen Li ◽  
Xiaojing Bi ◽  
Enxue Shi ◽  
...  

An efficient, practical and scalable protocol to prepare chiral 2,3-dihydroquinazolinones was developed under catalysis of spirocyclic SPINOL-phosphoric acid.


Author(s):  
Alexander Gak ◽  
Svetlana Kuznetsova ◽  
Yulia Nelyubina ◽  
Alexander A. Korlyukov ◽  
Han Li ◽  
...  

2016 ◽  
Vol 88 (3) ◽  
pp. 207-214 ◽  
Author(s):  
Elisabetta Manoni ◽  
Assunta De Nisi ◽  
Marco Bandini

AbstractThe regio- and stereoselective dearomatization of indoles is realized for the first time by combining readily available indolyl precursors and electron-rich allenes, namely allenamides and aryloxyallenes. Inter- as well as intramolecular condensations were realized under gold and Brønsted acid catalysis providing a range of densely functionalized indoline and indolenine cores in high yields and excellent stereochemical outcome. Chemodivergent reaction profiles (Micheal-type addition vs. [2+2]-cycloaddition) were realized by a tailored design of both reaction conditions and functionalization of the reaction partners.


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