H5PV2Mo10O40 Polyoxometalate Encapsulated in NU-1000 Metal–Organic Framework for Aerobic Oxidation of a Mustard Gas Simulant

2019 ◽  
Vol 3 (1) ◽  
pp. 658-664 ◽  
Author(s):  
Cassandra T. Buru ◽  
Megan C. Wasson ◽  
Omar K. Farha
Keyword(s):  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Mustard Gas ◽  
Metal Organic ◽  
Organic Framework

A novel copper(ii)–lanthanum(iii) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes

2016 ◽  
Vol 6 (11) ◽  
pp. 3727-3736 ◽  
Author(s):  
P. Cancino ◽  
A. Vega ◽  
Andrea Santiago-Portillo ◽  
Sergio Navalon ◽  
Mercedes Alvaro ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Selective Catalyst ◽  
Pyridinedicarboxylic Acid ◽  
Metal Organic ◽  
Organic Framework

The synthesis and catalytic activity of a novel heteronuclear CuII and LaIII metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported.

A cerium-based metal–organic framework having inherent oxidase-like activity applicable for colorimetric sensing of biothiols and aerobic oxidation of thiols

CrystEngComm ◽  
2017 ◽  
Vol 19 (39) ◽  
pp. 5915-5925 ◽  
Author(s):  
Rana Dalapati ◽  
Balasubramanian Sakthivel ◽  
Manoj K. Ghosalya ◽  
Amarajothi Dhakshinamoorthy ◽  
Shyam Biswas
Keyword(s):  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Colorimetric Sensing ◽  
Metal Organic ◽  
Organic Framework

A cerium-based MOF exhibits oxidase-like activity for colorimetric sensing of biothiols and aerobic oxidation of thiols.

scholarly journals Frontispiz: Palladium Catalysis for Aerobic Oxidation Systems Using Robust Metal–Organic Framework

2019 ◽  
Vol 131 (48) ◽  
Author(s):  
Jiawei Li ◽  
Jianhua Liao ◽  
Yanwei Ren ◽  
Chi Liu ◽  
Chenglong Yue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Palladium Catalysis ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Air oxidation of sulfur mustard gas simulants using a pyrene-based metal–organic framework photocatalyst

2019 ◽  
Vol 10 ◽  
pp. 2422-2427 ◽  
Author(s):  
Ghada Ayoub ◽  
Mihails Arhangelskis ◽  
Xuan Zhang ◽  
Florencia Son ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Oxidative Degradation ◽  
Chemical Warfare Agents ◽  
Mustard Gas ◽  
Air Oxidation ◽  
Substitution Pattern ◽  
Warfare Agents ◽  
Metal Organic ◽  
Organic Framework

We demonstrate a microporous metal–organic framework NU-400 based on a 2,7-disubstituted pyrene linker as a highly efficient photosensitizer for generating singlet oxygen and subsequent oxidative degradation of chemical warfare agents (CWAs). The high activity of NU-400 permits photocatalytic conversion of the 2-chloroethyl ethyl sulfide (CEES) mustard gas simulant into a benign sulfoxide derivative, in air, with less than 15 minutes’ half-life. This is a considerable improvement to NU-1000, based on a 1,3,6,8-tetrasubstituted pyrene unit, demonstrating how variation of the substitution pattern of a metal–organic framework linker permits modification of its photoactive behavior.

Selective Aerobic Oxidation of a Metal–Organic Framework Boosts Thermodynamic and Kinetic Propylene/Propane Selectivity

2019 ◽  
Vol 131 (23) ◽  
pp. 7774-7778 ◽  
Author(s):  
Yu Wang ◽  
Ning‐Yu Huang ◽  
Xue‐Wen Zhang ◽  
Hai He ◽  
Rui‐Kang Huang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Metal Organic ◽  
Selective Aerobic Oxidation ◽  
Organic Framework
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