scholarly journals A Phosphonium Ylide as an Ionic Nucleophilic Catalyst for Primary Hydroxyl Group Selective Acylation of Diols

ACS Catalysis ◽  
2017 ◽  
Vol 7 (9) ◽  
pp. 6150-6154 ◽  
Author(s):  
Yasunori Toda ◽  
Tomoyuki Sakamoto ◽  
Yutaka Komiyama ◽  
Ayaka Kikuchi ◽  
Hiroyuki Suga
Keyword(s):  
Hydroxyl Group ◽  
Primary Hydroxyl ◽  
Selective Acylation

LYCOCTONINE AND ITS OXIDATION PRODUCTS

1952 ◽  
Vol 30 (9) ◽  
pp. 627-645 ◽  
Author(s):  
O. E. Edwards ◽  
Léo Marion
Keyword(s):  
The Other ◽  
Oxidation Products ◽  
Hydroxyl Group ◽  
Ultraviolet Spectra ◽  
Primary Hydroxyl ◽  
Alkyl Groups ◽  
Methylene Group

The ultraviolet spectra, basic strengths, and N-alkyl groups of the aconite alkaloids are discussed. Pyropseudaconine has been shown to contain a conjugated system. The formulation C19H19–2,(OH)3,(OCH3)4NC2H5 has been confirmed for lycoctonine. Study of its oxidation products has shown that lycoctonine has a methylene group adjacent to the nitrogen and a primary hydroxyl group. The two remaining hydroxyls have been shown to be vicinal, with one probably secondary and the other tertiary. A carbinolamine structure is suggested for hydroxylycoctonine. The new bases, isolycoctonine, desoxylycoctonine, and des-(oxymethylene)-lycoctonine are described.

scholarly journals SYNTHESIS OF 1,2;3,4-DI-O-ISOPROPYLIDENE-6- O-[4-(1H-AZOL-1-YLMETHYL) PHENYL]- ¯-D-GALACTOPYRANOSE AND 1,2,3,4-TETRA-O-ACETYL-6- O-[4-(1H-AZOL-1- YLMETHYL)PHENYL]-¯-D-GLUCOPYRANOSE

2017 ◽  
Vol 17 (5) ◽  
pp. 122-128
Author(s):  
Z.P. Belousova ◽  
P.P. Purygin ◽  
A.P. Tyurin
Keyword(s):  
Hydroxyl Group ◽  
Hydroxyl Groups ◽  
Secondary Hydroxyl ◽  
Primary Hydroxyl ◽  
Derivatives Of

Derivatives of D-galactose and D-glucose substituted for the primary hydroxyl group, which contain an aglycone azolylmethylphenyl fragments (for imidazole, 1,2,4-triazole, benzimidazole and benzotriazole) has been synthesized. Toprotect the secondary hydroxyl groups of monosaccharides acetyl and isopropylidene groups were used.

Propylene oxide end-capping route to primary hydroxyl group dominated CO2-polyol

Polymer ◽  
2018 ◽  
Vol 153 ◽  
pp. 167-172
Author(s):  
Shuangbin Fu ◽  
Yusheng Qin ◽  
Lijun Qiao ◽  
Xianhong Wang ◽  
Fosong Wang
Keyword(s):  
Propylene Oxide ◽  
Hydroxyl Group ◽  
Primary Hydroxyl ◽  
End Capping

ChemInform Abstract: Synthesis of Aralkyl Peroxides with a Primary Hydroxyl Group.

ChemInform ◽  
1987 ◽  
Vol 18 (11) ◽  
Author(s):  
O. I. GEVUS' ◽  
M. A. DIKII ◽  
V. A. PUCHIN
Keyword(s):  
Hydroxyl Group ◽  
Primary Hydroxyl
Sign in / Sign up

Export Citation Format

Share Document