scholarly journals Visible-Light Photoredox Enables Ketone Carbonyl Alkylation for Easy Access to Tertiary Alcohols

ACS Catalysis ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 9009-9014 ◽  
Author(s):  
Minh Duy Vu ◽  
Mrinmoy Das ◽  
Aoxin Guo ◽  
Zi-En Ang ◽  
Miloš D̵okić ◽  
...  
Photonics ◽  
2019 ◽  
Vol 6 (3) ◽  
pp. 85 ◽  
Author(s):  
Arslan Khalid ◽  
Hafiz Muhammad Asif ◽  
Konstantin I. Kostromitin ◽  
Sattam Al-Otaibi ◽  
Kazi Mohammed Saidul Huq ◽  
...  

Visible Light Communication (VLC) is a data communication technology that modulates the intensity of the light to transmit the information mostly by means of Light Emitting Diodes (LEDs). The data rate is mainly throttled by the limited bandwidth of the LEDs. To combat, Multi-carrier Code Division Multiple Access (MC-CDMA) is a favorable technique for achieving higher data rates along with reduced Inter-Symbol Interference (ISI) and easy access to multi-users at the cost of slightly reduced compromised spectral efficiency and Multiple Access Interference (MAI). In this article, a multi-user VLC system is designed using a Discrete Wavelet Transform (DWT) that eradicates the use of cyclic prefix due to the good orthogonality and time-frequency localization properties of wavelets. Moreover, the design also comprises suitable signature codes, which are generated by employing double orthogonality depending upon Walsh codes and Wavelet Packets. The proposed multi-user system is simulated in MATLAB software and its overall performance is assessed using line-of-sight (LoS) and non-line-of-sight (NLoS) configurations. Furthermore, two sub-optimum multi-users detection schemes such as zero forcing (ZF) and minimum-mean-square-error (MMSE) are also used at the receiver. The simulated results illustrate that the doubly orthogonal signature waveform-based DWT-MC-CDMA with MMSE detection scheme outperforms the Walsh code-based multi-user system.


2018 ◽  
Vol 54 (78) ◽  
pp. 11017-11020 ◽  
Author(s):  
Xiao Xu ◽  
Qing-Qiang Min ◽  
Na Li ◽  
Feng Liu

A metal-free, mild, and simple protocol is developed for the synthesis of tertiary alcohols bearing tri-/difluoromethyl groups upon visible-light irradiation.


Author(s):  
Sandrine M. Hell ◽  
Claudio F. Meyer ◽  
Andrés A. Trabanco ◽  
Véronique Gouverneur

2021 ◽  
Vol 57 (82) ◽  
pp. 10783-10786
Author(s):  
Benjamin Rui Peng Yip ◽  
Kumar Bhaskar Pal ◽  
Junjie Desmond Lin ◽  
Yuan Xu ◽  
Mrinmoy Das ◽  
...  

An organo-photocatalyst catalyzed allylation of aryl ketones and aldehydes using readily available unactivated allylic substrates has been reported.


2021 ◽  
Author(s):  
Tobias Brandhofer ◽  
Martin Stinglhamer ◽  
Volker Derdau ◽  
Maria Mendez-Perez ◽  
Christoph Pöverlein ◽  
...  

A visible light-mediated photocatalyzed C-C-bond forming method for the benzylic C-H functionalization of phenolether containing synthetic building blocks based on a radical-cation/deprotonation strategy is reported. This method allows the mild,...


ChemInform ◽  
2012 ◽  
Vol 43 (27) ◽  
pp. no-no
Author(s):  
Guolei Zhao ◽  
Chao Yang ◽  
Lin Guo ◽  
Hongnan Sun ◽  
Chao Chen ◽  
...  

2017 ◽  
Vol 53 (61) ◽  
pp. 8533-8536 ◽  
Author(s):  
Fei Gao ◽  
Jiu-Tao Wang ◽  
Lin-Lin Liu ◽  
Na Ma ◽  
Chao Yang ◽  
...  

An efficient strategy for the easy access to carbonylated heteroaromatic compounds has been developed via a visible-light-promoted intramolecular decarboxylative cyclization reaction of o-alkynylated carboxylic acids.


2019 ◽  
Vol 21 (6) ◽  
pp. 1799-1803 ◽  
Author(s):  
Yongzhen Han ◽  
Yunhe Jin ◽  
Min Jiang ◽  
Haijun Yang ◽  
Hua Fu

Sign in / Sign up

Export Citation Format

Share Document