Impact of Specific Interactions Among Reactive Surface Intermediates and Confined Water on Epoxidation Catalysis and Adsorption in Lewis Acid Zeolites

ACS Catalysis ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 10951-10962 ◽  
Author(s):  
Daniel T. Bregante ◽  
David W. Flaherty
Keyword(s):  
Lewis Acid ◽  
Specific Interactions ◽  
Confined Water ◽  
Reactive Surface ◽  
Acid Zeolites ◽  
Surface Intermediates

Influence of confining environment polarity on ethanol dehydration catalysis by Lewis acid zeolites

2018 ◽  
Vol 365 ◽  
pp. 213-226 ◽  
Author(s):  
Jason S. Bates ◽  
Rajamani Gounder
Keyword(s):  
Lewis Acid ◽  
Ethanol Dehydration ◽  
Acid Zeolites

Scaling Relationships for Molecular Adsorption and Dissociation in Lewis Acid Zeolites

2016 ◽  
Vol 120 (12) ◽  
pp. 6714-6722 ◽  
Author(s):  
Brandon C. Bukowski ◽  
Jeffrey Greeley
Keyword(s):  
Lewis Acid ◽  
Molecular Adsorption ◽  
Scaling Relationships ◽  
Acid Zeolites ◽  
Adsorption And Dissociation

scholarly journals Lewis Acid Zeolites for Biomass Conversion: Perspectives and Challenges on Reactivity, Synthesis, and Stability

2016 ◽  
Vol 7 (1) ◽  
pp. 663-692 ◽  
Author(s):  
Helen Y. Luo ◽  
Jennifer D. Lewis ◽  
Yuriy Román-Leshkov
Keyword(s):  
Lewis Acid ◽  
Biomass Conversion ◽  
Acid Zeolites

A Continuous Flow Strategy for the Coupled Transfer Hydrogenation and Etherification of 5-(Hydroxymethyl)furfural using Lewis Acid Zeolites

ChemSusChem ◽  
2014 ◽  
Vol 7 (8) ◽  
pp. 2255-2265 ◽  
Author(s):  
Jennifer D. Lewis ◽  
Stijn Van de Vyver ◽  
Anthony J. Crisci ◽  
William R. Gunther ◽  
Vladimir K. Michaelis ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Continuous Flow ◽  
Transfer Hydrogenation ◽  
Hydroxymethyl Furfural ◽  
Acid Zeolites

Isomerization of n-butane over acid zeolites Role of Broensted and Lewis acid sites

1999 ◽  
Vol 185 (1) ◽  
pp. 123-130 ◽  
Author(s):  
E Baburek
Keyword(s):  
Lewis Acid ◽  
Acid Sites ◽  
Lewis Acid Sites ◽  
Acid Zeolites

A low-deactivation-rate Lewis acid zeolite prepared in an alkali metal ion-containing system for alkene epoxidation

RSC Advances ◽  
2016 ◽  
Vol 6 (100) ◽  
pp. 98514-98519 ◽  
Author(s):  
Kai-Rui Fu ◽  
Ji-Kang Yao ◽  
Qiang Xiao ◽  
Hai-Xia Liu ◽  
Tian-Duo Li ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Lewis Acid ◽  
Metal Ion ◽  
Catalytic Performance ◽  
Alkali Metal Ion ◽  
Deactivation Rate ◽  
Acid Zeolites

The best catalytic performance among the currently reported TS-1 Lewis acid zeolites is achieved due to its durable catalytic life.

Cascade of Liquid-Phase Catalytic Transfer Hydrogenation and Etherification of 5-Hydroxymethylfurfural to Potential Biodiesel Components over Lewis Acid Zeolites

ChemCatChem ◽  
2014 ◽  
Vol 6 (2) ◽  
pp. 508-513 ◽  
Author(s):  
Jungho Jae ◽  
Eyas Mahmoud ◽  
Raul F. Lobo ◽  
Dionisios G. Vlachos
Keyword(s):  
Liquid Phase ◽  
Lewis Acid ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Acid Zeolites ◽  
Catalytic Transfer

scholarly journals Selective active site placement in Lewis acid zeolites and implications for catalysis of oxygenated compounds

2020 ◽  
Vol 11 (37) ◽  
pp. 10225-10235
Author(s):  
Aída Rodríguez-Fernández ◽  
John R. Di Iorio ◽  
Cecilia Paris ◽  
Mercedes Boronat ◽  
Avelino Corma ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Active Site ◽  
Acid Sites ◽  
Lewis Acid Sites ◽  
Oxygenated Compounds ◽  
Acid Zeolites ◽  
Selective Incorporation ◽  
High Silica ◽  
High Silica Zeolites

The selective incorporation of isolated framework Lewis acid sites in specific crystallographic positions in high-silica zeolites was achieved successfully by applying a rationalized post-synthetic grafting methodology.

Ordered Hydrogen-Bonded Alcohol Networks Confined in Lewis Acid Zeolites Accelerate Transfer Hydrogenation Turnover Rates

2020 ◽  
Vol 142 (45) ◽  
pp. 19379-19392
Author(s):  
John R. Di Iorio ◽  
Blake A. Johnson ◽  
Yuriy Román-Leshkov
Keyword(s):  
Lewis Acid ◽  
Transfer Hydrogenation ◽  
Turnover Rates ◽  
Acid Zeolites ◽  
Hydrogen Bonded

In Situ Methods for Identifying Reactive Surface Intermediates during Hydrogenolysis Reactions: C–O Bond Cleavage on Nanoparticles of Nickel and Nickel Phosphides

2019 ◽  
Vol 141 (42) ◽  
pp. 16671-16684 ◽  
Author(s):  
Megan E. Witzke ◽  
Abdulrahman Almithn ◽  
Christian L. Coonrod ◽  
Mark D. Triezenberg ◽  
David D. Hibbitts ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Reactive Surface ◽  
Nickel Phosphides ◽  
Surface Intermediates ◽  
In Situ Methods
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