Synergistic Effect of Hydrogen Bonding and π–π Stacking Enables Long Cycle Life in Organic Electrode Materials

2021 ◽  
Vol 6 (2) ◽  
pp. 643-649
Author(s):  
Madison R. Tuttle ◽  
Shelby T. Davis ◽  
Shiyu Zhang
Keyword(s):  
Hydrogen Bonding ◽  
Synergistic Effect ◽  
Electrode Materials ◽  
Cycle Life ◽  
Long Cycle ◽  
Long Cycle Life ◽  
Π Stacking ◽  
Organic Electrode

scholarly journals Synergistic Effect of Hydrogen Bonding and π-π Stacking Enables Long Cycle Life in Organic Electrode Materials

2020 ◽  
Author(s):  
Madison R. Tuttle ◽  
Shelby Davis ◽  
Shiyu Zhang
Keyword(s):  
Hydrogen Bonding ◽  
Electrode Materials ◽  
Variable Temperature ◽  
Interaction Strength ◽  
Lithium Ion ◽  
Long Cycle Life ◽  
Π Stacking ◽  
New Strategy ◽  
Organic Electrode ◽  
Donor Acceptor

Small-molecule organic compounds have emerged as attractive candidates for energy storage in lithium-ion batteries due to their sustainability and modularity. To develop generalizable design principles for organic electrode materials (OEMs), we investigated the correlation between electrochemical performance and addition of functional groups that promote synergistic hydrogen bonding and π-π stacking using a series of quinone-fused aza-phenazines (QAPs) with different hydrogen bonding donor/acceptor arrays. The QAP containing the most hydrogen bonding groups (<b>3</b>) exhibits the best performance with discharge capacities of 145 mAh g<sup>-1</sup> at 2C with 82% capacity retention over 1000 cycles. The performance of <b>3</b> is attributed to the strategically incorporated -OH and -NH<sub>2</sub> groups, which facilitate strong intermolecular interactions and a tightly packed 2D structure. The intermolecular interaction strength was evaluated using variable temperature 1D <sup>1</sup>H NMR and 2D <sup>1</sup>H-<sup>1</sup>H NOESY, offering a new strategy to help understand and predict the performance of OEMs with hydrogen bonding motifs.

scholarly journals Synergistic Effect of Hydrogen Bonding and π-π Stacking Enables Long Cycle Life in Organic Electrode Materials

2020 ◽  
Author(s):  
Madison R. Tuttle ◽  
Shelby Davis ◽  
Shiyu Zhang
Keyword(s):  
Hydrogen Bonding ◽  
Electrode Materials ◽  
Variable Temperature ◽  
Interaction Strength ◽  
Lithium Ion ◽  
Long Cycle Life ◽  
Π Stacking ◽  
New Strategy ◽  
Organic Electrode ◽  
Donor Acceptor

Small-molecule organic compounds have emerged as attractive candidates for energy storage in lithium-ion batteries due to their sustainability and modularity. To develop generalizable design principles for organic electrode materials (OEMs), we investigated the correlation between electrochemical performance and addition of functional groups that promote synergistic hydrogen bonding and π-π stacking using a series of quinone-fused aza-phenazines (QAPs) with different hydrogen bonding donor/acceptor arrays. The QAP containing the most hydrogen bonding groups (<b>3</b>) exhibits the best performance with discharge capacities of 145 mAh g<sup>-1</sup> at 2C with 82% capacity retention over 1000 cycles. The performance of <b>3</b> is attributed to the strategically incorporated -OH and -NH<sub>2</sub> groups, which facilitate strong intermolecular interactions and a tightly packed 2D structure. The intermolecular interaction strength was evaluated using variable temperature 1D <sup>1</sup>H NMR and 2D <sup>1</sup>H-<sup>1</sup>H NOESY, offering a new strategy to help understand and predict the performance of OEMs with hydrogen bonding motifs.

α-Fe2O3/rGO nanospindles as electrode materials for supercapacitors with long cycle life

2018 ◽  
Vol 107 ◽  
pp. 391-396 ◽  
Author(s):  
Yidi Dong ◽  
Lei Xing ◽  
Fang Hu ◽  
Ahmad Umar ◽  
Xiang Wu
Keyword(s):  
Electrode Materials ◽  
Cycle Life ◽  
Long Cycle ◽  
Long Cycle Life

Super long-life supercapacitor electrode materials based on hierarchical porous hollow carbon microcapsules

RSC Advances ◽  
2015 ◽  
Vol 5 (106) ◽  
pp. 87077-87083 ◽  
Author(s):  
Fen Ran ◽  
Xuanxuan Zhang ◽  
Yuansen Liu ◽  
Kuiwen Shen ◽  
Xiaoqin Niu ◽  
...  
Keyword(s):  
Electrode Materials ◽  
Cycle Life ◽  
Supercapacitor Electrode ◽  
Active Materials ◽  
Long Cycle ◽  
Long Cycle Life ◽  
Hierarchical Porous ◽  
Long Life ◽  
Hollow Carbon ◽  
Supercapacitor Electrode Materials

Remarkable supercapacitor electrodes with a high specific supercapacitance and a super long cycle life were achieved by using hierarchical porous hollow carbon microcapsules (HPHCMs) as active materials.

scholarly journals Synchronous exfoliation and assembly of graphene on 3D Ni(OH)2 for supercapacitors

2016 ◽  
Vol 52 (91) ◽  
pp. 13373-13376 ◽  
Author(s):  
Liguo Ma ◽  
Maojun Zheng ◽  
Shaohua Liu ◽  
Qiang Li ◽  
Yuxiu You ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
Electrode Materials ◽  
Rate Capability ◽  
Cycle Life ◽  
High Quality ◽  
Exfoliate Graphite ◽  
Long Cycle ◽  
Long Cycle Life

We present a facile strategy to synchronously exfoliate graphite and assemble high-quality graphene on 3D Ni(OH)2 surfaces. When serving as electrode materials for supercapacitors, the resulting 3D Ni(OH)2/graphene composites exhibited excellent specific capacitance, remarkable rate capability and super-long cycle life.

Anthraquinone‐Based Oligomer as a Long Cycle‐Life Organic Electrode Material for Use in Rechargeable Batteries

ChemPhysChem ◽  
2019 ◽  
Vol 20 (7) ◽  
pp. 967-971 ◽  
Author(s):  
Masaru Yao ◽  
Hikaru Sano ◽  
Hisanori Ando ◽  
Tetsu Kiyobayashi ◽  
Nobuhiko Takeichi
Keyword(s):  
Electrode Material ◽  
Rechargeable Batteries ◽  
Cycle Life ◽  
Long Cycle ◽  
Long Cycle Life ◽  
Organic Electrode

scholarly journals Long Cycle-life Organic Electrode Material based on an Ionic Naphthoquinone Derivative for Rechargeable Batteries

2014 ◽  
Vol 56 ◽  
pp. 228-236 ◽  
Author(s):  
Masaru Yao ◽  
Tatsuhiro Numoto ◽  
Miho Araki ◽  
Hisanori Ando ◽  
Hiroyuki T. Takeshita ◽  
...  
Keyword(s):  
Electrode Material ◽  
Rechargeable Batteries ◽  
Cycle Life ◽  
Long Cycle ◽  
Long Cycle Life ◽  
Organic Electrode ◽  
Naphthoquinone Derivative

An aqueous rechargeable lithium ion battery with long cycle life and overcharge self-protection

2021 ◽  
Author(s):  
Zhiguo Hou ◽  
Lei Zhang ◽  
Jianwu Chen ◽  
Yali Xiong ◽  
Xueqian Zhang ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Cycling Stability ◽  
Cycle Life ◽  
Long Cycle ◽  
Full Cell ◽  
Long Cycle Life ◽  
Excellent Cycling Stability ◽  
Self Protection

Zn2+ added into electrolyte can effectively suppress H2 evolution. Therefore, a LiMn2O4/NaTi2(PO4)3 full cell exhibits enhanced overcharging performance and excellent cycling stability up to 10 000 cycles.

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