scholarly journals The Predominance of Hydrogen Evolution on Transition Metal Sulfides and Phosphides under CO2 Reduction Conditions: An Experimental and Theoretical Study

2018 ◽  
Vol 3 (6) ◽  
pp. 1450-1457 ◽  
Author(s):  
Alan T. Landers ◽  
Meredith Fields ◽  
Daniel A. Torelli ◽  
Jianping Xiao ◽  
Thomas R. Hellstern ◽  
...  
Nanoscale ◽  
2021 ◽  
Author(s):  
Wenjun He ◽  
Jianing Cheng ◽  
Yaohui Gao ◽  
Caichi Liu ◽  
Jianling Zhao ◽  
...  

The development of earth-abundant transition metal sulfides electrocatalysts with excellent activity and stability toward alkaline hydrogen evolution reaction (HER) is critical but challenging. Iron-based sulfides are favored due to their...


CrystEngComm ◽  
2021 ◽  
Author(s):  
Xianpei Ren ◽  
Qingbo Wei ◽  
Fei Wu ◽  
Yonghua Wang ◽  
qiang li

Transition metal sulfides, such as molybdenum sulfide and vanadium sulfide, have recently attracted substantial attention due to their potential application to the catalysis of the hydrogen evolution reaction (HER). Alloying...


2009 ◽  
Vol 140 ◽  
pp. 219-231 ◽  
Author(s):  
Jacob Bonde ◽  
Poul G. Moses ◽  
Thomas F. Jaramillo ◽  
Jens K. Nørskov ◽  
Ib Chorkendorff

2011 ◽  
Vol 6 (1) ◽  
pp. 290 ◽  
Author(s):  
Shaohua Shen ◽  
Xiaobo Chen ◽  
Feng Ren ◽  
Coleman X Kronawitter ◽  
Samuel S Mao ◽  
...  

2008 ◽  
Vol 73 (8-9) ◽  
pp. 945-955 ◽  
Author(s):  
Luděk Kaluža ◽  
Miroslav Zdražil

The transition metals V, Cr, Mn, Fe, Co, Ni, Mo, Ru, Rh, Pd, W, Re, Os, Ir and Pt were deposited from aqueous solutions of their salts onto conventional γ-Al2O3 and unconventional TiO2 and ZrO2 supports by vacuum impregnation and characterized in their sulfided form by a model reaction of benzothiophene hydrodesulfurization. It was found that the TiO2 and ZrO2 supports influenced predominantly positively the resulting activity of relatively low-active metals (V, Cr, Mn, Fe, Co, Ni, Mo, Ru, W and Os), whereas the highly active metals (Rh, Pd, Ir, Pt and Re) were influenced slightly negatively or not at all by those supports compared with the γ-Al2O3-supported system. A significant effect of the supports on the hydrodesulfurization-activity ranking of the transition-metal sulfides studied was ascertained.


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