scholarly journals Significantly Enhanced Thermal Decomposition of Mechanically Activated Ammonium Perchlorate Coupling with Nano Copper Chromite

ACS Omega ◽  
2021 ◽  
Author(s):  
Dongdong Zhang ◽  
Qiang Li ◽  
Ruiqin Li ◽  
Hao Li ◽  
Hongxu Gao ◽  
...  

1971 ◽  
Vol 49 (17) ◽  
pp. 2827-2831 ◽  
Author(s):  
R. Gilbert ◽  
P. W. M. Jacobs

The thermal decomposition of perchloric acid has been investigated on five Harshaw catalysts: copper chromite, alumina, iron(III) oxide, copper(II) oxide, and manganese(IV) oxide (the last three being supported on alumina). Manganese(IV) oxide gave complex kinetics which were not fully analyzed but on the other four catalysts the reaction was.first order. Activation energies were: copper chromite, 54 kcal/mol; alumina, 28.8 kcal/mol; iron(III) oxide, 28.6 kcal/mol; copper(II) oxide, 39.0 kcal/mol. A mechanism is proposed for the decomposition which involves proton transfer to an accepter (typically an O2− ion) in the catalyst surface followed by decomposition of the ClO4− anion formed in this process. Some observations on the catalyzed thermal decomposition of ammonium perchlorate are presented.









2008 ◽  
Vol 33 (4) ◽  
pp. 266-270 ◽  
Author(s):  
Prajakta R. Patil ◽  
V. N. Krishnamurthy ◽  
Satyawati S. Joshi


Author(s):  
Hua Fang ◽  
Xueyong Guo ◽  
Liping Shi ◽  
Kehua Han ◽  
Jianxin Nie ◽  
...  


2021 ◽  
Vol 35 (5) ◽  
pp. 4447-4456
Author(s):  
Xiaoge Han ◽  
Linyu Zhou ◽  
Shaobo Cao ◽  
Liangliang Zhang ◽  
Guolei Xiang ◽  
...  


Author(s):  
Changping Guo ◽  
Yuewen Lu ◽  
Yuhao Tian ◽  
Hao Guo ◽  
Xingquan Zhang


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