Bonds, Bands, Charge-Transfer Excitations, and High-Temperature Superconductivity

Author(s):  
A. J. Freeman ◽  
S. Massidda ◽  
Jaejun Yu
2003 ◽  
Vol 17 (18n20) ◽  
pp. 3310-3314 ◽  
Author(s):  
John D. Dow ◽  
Dale R. Harshman

Cuprate-planes are not necessary and essential for high-temperature superconductivity: doped Sr 2 YRuO 6 superconducts fully at 23 K in its SrO layers once the Ru stops librating (the material begins superconducting at ≈ 49K). GdSr 2 Cu 2 RuO 8 superconducts near 45 K in its SrO layers, not in its cuprate-planes. By examining the charge transfer, we find that Tc increases with the number of layers n and with pressure p in the HgBa 2 Ca n-1 Cu n O 2n+2 compounds, as does the charge in the BaO layers (and not the charge in the cuprate-planes), indicating that the superconductivity is in the BaO layers. Four superconductors, including PrBa 2 Cu 3 O 7, were successfully predicted to superconduct not in their cuprate-planes, but in their BaO or SrO layers. The original claims that the superconductivity resides primarily in the cuprate-planes are invalid.


1991 ◽  
Vol 185-189 ◽  
pp. 701-702 ◽  
Author(s):  
C.W. Chu ◽  
P.H. Hor ◽  
Y.Y. Xue ◽  
G. Lin ◽  
R.L. Meng ◽  
...  

Physica B+C ◽  
1987 ◽  
Vol 148 (1-3) ◽  
pp. 212-217 ◽  
Author(s):  
A.J. Freeman ◽  
Jaejun Yu ◽  
S. Massidda ◽  
D.D. Koelling

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