Syntheses, Structures, and Photoluminescence of One-Dimensional Lanthanide Coordination Polymers with 2,4,6-Pyridinetricarboxylic Acid

2007 ◽  
Vol 7 (9) ◽  
pp. 1851-1857 ◽  
Author(s):  
Hong-Sheng Wang ◽  
Bin Zhao ◽  
Bin Zhai ◽  
Wei Shi ◽  
Peng Cheng ◽  
...  





2019 ◽  
Vol 75 (4) ◽  
pp. 422-432 ◽  
Author(s):  
Chao Bai ◽  
Bin Liu ◽  
Huai-Ming Hu ◽  
Jin-Dian Li ◽  
Xiaofang Wang ◽  
...  

Three series of lanthanide coordination polymers, namely catena-poly[[lanthanide(III)-μ2-(benzene-1,2-dicarboxylato)-μ2-[2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]] monohydrate], {[Ln(C8H4O4)(C22H14N3O2)]·H2O} n or {[Ln(1,2-bdc)(L)]·H2O} n , with lanthanide (Ln) = dysprosium (Dy, 1), holmium (Ho, 2) and erbium (Er, 3), poly[bis(μ2-benzene-1,3-dicarboxylato)bis[μ2-2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]dilanthanide(III)], [Ln2(C8H4O4)2(C22H14N3O2)2] n or [Ln2(1,3-bdc)2(L)2] n , with Ln = gadolinium (Gd, 4), Ho (5) and Er (6), and poly[(μ2-benzene-1,4-dicarboxylato)[μ2-2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]lanthanide(III)], [Ln(C8H4O4)(C22H14N3O2)] n or [Ln(1,4-bdc)(L)] n , with Ln = Dy (7), Ho (8), Er (9) and ytterbium (Yb, 10), were synthesized under hydrothermal conditions and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Compounds 1–3 possess one-dimensional loop chains with Ln2(COO)2 units, which are extended into three-dimensional (3D) supramolecular structures by π–π interactions. Isostructural compounds 5 and 6 show 6-connected 3D networks, with pcu topology consisting of Ln2(COO)2 units. Compounds 7–10 display 8-connected 3D frameworks with the topological type rob, consisting of Ln2(COO)2 units. The influence of the coordination orientations of the aromatic dicarboxylate groups on the crystal structures is discussed.



2020 ◽  
Vol 44 (18) ◽  
pp. 7270-7276 ◽  
Author(s):  
Guo Peng ◽  
Yue Chen ◽  
Bo Li

Four one-dimensional lanthanide coordination polymers constructed from Ln2 dimers showing single molecule magnet behavior and photoluminescence are reported.



2015 ◽  
Vol 44 (10) ◽  
pp. 4640-4647 ◽  
Author(s):  
Chang Feng ◽  
Jing-Wen Sun ◽  
Peng-Fei Yan ◽  
Yu-Xin Li ◽  
Tian-Qi Liu ◽  
...  

l-Di-2-thenoyltartaric acid mix-lanthanide coordination polymers with one-dimensional ladder-like chain structures present color-tunable and white-light emission upon varying the excitation wavelength.



2003 ◽  
Vol 655 (2) ◽  
pp. 339-342 ◽  
Author(s):  
Xu Haitao ◽  
Zheng Nengwu ◽  
Jin Xianglin ◽  
Yang Ruyi ◽  
Wu Yonggang ◽  
...  


2006 ◽  
Vol 59 (18) ◽  
pp. 2075-2081
Author(s):  
Zhen-Feng Chen ◽  
Liang-Cai Yu ◽  
Yan-Cheng Liu ◽  
Hong Liang ◽  
Chun-Shan Zhou ◽  
...  


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