Diffusion Path of Oxide Ions in an Oxide Ion Conductor La0.64(Ti0.92Nb0.08)O2.99with a Double Perovskite-Type Structure

2007 ◽  
Vol 19 (13) ◽  
pp. 3260-3264 ◽  
Author(s):  
Roushown Ali ◽  
Masatomo Yashima ◽  
Fujio Izumi
2005 ◽  
Vol 242-244 ◽  
pp. 159-168 ◽  
Author(s):  
Katsuyoshi Kakinuma ◽  
Hiroshi Yamamura ◽  
Tooru Atake

We have discovered a high oxide ion conductor within the perovskite-type (Ba1-x-ySrxLay)InO2.5+y/2 solid-solution system. The system was derived from brownmillerite-type Ba2In2O5, which possessed a ordered oxide ion vacancies. When we doped La3+ into the Ba site, the vacancy changed to a disordered state. The oxide ion conductivity increased with the amount of doped La3+, reaching a maximum value of 0.12 (S/cm) at 800 oC in (Ba0.3Sr0.2La0.5)InO2.75, a level exceeding that of yttria-stabilized zirconia. The oxide ion conductivity of this system was strongly dependent on the unit cell free volume, which appears to be the key parameter governing oxide ion mobility.


2005 ◽  
Vol 87 (22) ◽  
pp. 221909 ◽  
Author(s):  
Masatomo Yashima ◽  
Daiju Ishimura

2016 ◽  
Vol 16 (5) ◽  
pp. 2535-2541 ◽  
Author(s):  
Igor Djerdj ◽  
Jasminka Popović ◽  
Suraj Mal ◽  
Tobias Weller ◽  
Marko Nuskol ◽  
...  

2019 ◽  
Vol 25 (2) ◽  
pp. 1701-1708 ◽  
Author(s):  
Shota Nakayama ◽  
Shin-ichi Hashimoto ◽  
Kazuhisa Sato ◽  
Keiji Yashiro ◽  
Koji Amezawa ◽  
...  

2017 ◽  
Vol 121 (39) ◽  
pp. 21272-21280 ◽  
Author(s):  
Ayaka Fujimoto ◽  
Masatomo Yashima ◽  
Kotaro Fujii ◽  
James R. Hester

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