scholarly journals Preparation and characterization of a new perovskite-type oxide ion conductor KN b1-xMgxO3-δ

2003 ◽  
Vol 52 (6) ◽  
pp. 1474
Author(s):  
Xiang Jun ◽  
Li Li-Ping ◽  
Su Wen-Hui

2019 ◽  
Vol 25 (2) ◽  
pp. 1701-1708 ◽  
Author(s):  
Shota Nakayama ◽  
Shin-ichi Hashimoto ◽  
Kazuhisa Sato ◽  
Keiji Yashiro ◽  
Koji Amezawa ◽  
...  






2005 ◽  
Vol 242-244 ◽  
pp. 159-168 ◽  
Author(s):  
Katsuyoshi Kakinuma ◽  
Hiroshi Yamamura ◽  
Tooru Atake

We have discovered a high oxide ion conductor within the perovskite-type (Ba1-x-ySrxLay)InO2.5+y/2 solid-solution system. The system was derived from brownmillerite-type Ba2In2O5, which possessed a ordered oxide ion vacancies. When we doped La3+ into the Ba site, the vacancy changed to a disordered state. The oxide ion conductivity increased with the amount of doped La3+, reaching a maximum value of 0.12 (S/cm) at 800 oC in (Ba0.3Sr0.2La0.5)InO2.75, a level exceeding that of yttria-stabilized zirconia. The oxide ion conductivity of this system was strongly dependent on the unit cell free volume, which appears to be the key parameter governing oxide ion mobility.



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