Fitting and Interpreting Transition-Metal Nanocluster Formation and Other Sigmoidal-Appearing Kinetic Data: A More Thorough Testing of Dispersive Kinetic vs Chemical-Mechanism-Based Equations and Treatments for 4-Step Type Kinetic Data

Eric E. Finney; Richard G. Finke

doi:10.1021/cm901142p

Fitting and Interpreting Transition-Metal Nanocluster Formation and Other Sigmoidal-Appearing Kinetic Data: A More Thorough Testing of Dispersive Kinetic vs Chemical-Mechanism-Based Equations and Treatments for 4-Step Type Kinetic Data

Chemistry of Materials ◽

10.1021/cm901142p ◽

2009 ◽

Vol 21 (19) ◽

pp. 4468-4479 ◽

Cited By ~ 41

Author(s):

Eric E. Finney ◽

Richard G. Finke

Keyword(s):

Transition Metal ◽

Kinetic Data ◽

Chemical Mechanism ◽

Metal Nanocluster ◽

Step Type

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Reply to Comment on “Fitting and Interpreting Transition-Metal Nanocluster Formation and Other Sigmoidal-Appearing Kinetic Data: A More Thorough Testing of Dispersive Kinetic vs Chemical-Mechanism-Based Equations and Treatments for 4-Step Type Kinetic Data”

Chemistry of Materials ◽

10.1021/cm903884p ◽

2010 ◽

Vol 22 (8) ◽

pp. 2687-2688 ◽

Cited By ~ 5

Author(s):

Eric E. Finney ◽

Richard G Finke

Keyword(s):

Transition Metal ◽

Kinetic Data ◽

Chemical Mechanism ◽

Metal Nanocluster ◽

Step Type

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Comment on “Fitting and Interpreting Transition-Metal Nanocluster Formation and Other Sigmoidal-Appearing Kinetic Data: A More Thorough Testing of Dispersive Kinetic vs Chemical-Mechanism-Based Equations and Treatments for 4-Step Type Kinetic Data”

Chemistry of Materials ◽

10.1021/cm9026489 ◽

2010 ◽

Vol 22 (8) ◽

pp. 2685-2686 ◽

Cited By ~ 3

Author(s):

Peter J. Skrdla

Keyword(s):

Transition Metal ◽

Kinetic Data ◽

Chemical Mechanism ◽

Metal Nanocluster ◽

Step Type

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The Four-Step, Double-Autocatalytic Mechanism for Transition-Metal Nanocluster Nucleation, Growth, and Then Agglomeration: Metal, Ligand, Concentration, Temperature, and Solvent Dependency Studies

Chemistry of Materials ◽

10.1021/cm071088j ◽

2008 ◽

Vol 20 (5) ◽

pp. 1956-1970 ◽

Cited By ~ 52

Author(s):

Eric E. Finney ◽

Richard G. Finke

Keyword(s):

Transition Metal ◽

Ligand Concentration ◽

Metal Nanocluster ◽

Metal Ligand ◽

Autocatalytic Mechanism ◽

Nucleation Growth

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Transition-Metal Nanocluster Kinetic and Mechanistic Studies Emphasizing Nanocluster Agglomeration: Demonstration of a Kinetic Method That Allows Monitoring of All Three Phases of Nanocluster Formation and Aging

Chemistry of Materials ◽

10.1021/cm0400637 ◽

2004 ◽

Vol 16 (20) ◽

pp. 3972-3972 ◽

Cited By ~ 10

Author(s):

Brooks J. Hornstein ◽

Richard G. Finke

Keyword(s):

Transition Metal ◽

Kinetic Method ◽

Mechanistic Studies ◽

Metal Nanocluster ◽

Three Phases

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Additional Investigations of a New Kinetic Method To Follow Transition-Metal Nanocluster Formation, Including the Discovery of Heterolytic Hydrogen Activation in Nanocluster Nucleation Reactions

Chemistry of Materials ◽

10.1021/cm0006852 ◽

2001 ◽

Vol 13 (2) ◽

pp. 312-324 ◽

Cited By ~ 86

Author(s):

Jason A. Widegren ◽

John D. Aiken ◽

Saim Özkar ◽

Richard G. Finke

Keyword(s):

Transition Metal ◽

Kinetic Method ◽

Hydrogen Activation ◽

Metal Nanocluster

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Long‐Life Room‐Temperature Sodium–Sulfur Batteries by Virtue of Transition‐Metal‐Nanocluster–Sulfur Interactions

Angewandte Chemie International Edition ◽

10.1002/anie.201811080 ◽

2019 ◽

Vol 58 (5) ◽

pp. 1484-1488 ◽

Cited By ~ 53

Author(s):

Bin‐Wei Zhang ◽

Tian Sheng ◽

Yun‐Xiao Wang ◽

Shulei Chou ◽

Kenneth Davey ◽

...

Keyword(s):

Transition Metal ◽

Room Temperature ◽

Metal Nanocluster ◽

Long Life ◽

Sodium Sulfur

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Is There a Minimal Chemical Mechanism Underlying Classical Avrami-Erofe’ev Treatments of Phase-Transformation Kinetic Data?

Chemistry of Materials ◽

10.1021/cm9018716 ◽

2009 ◽

Vol 21 (19) ◽

pp. 4692-4705 ◽

Cited By ~ 85

Author(s):

Eric E. Finney ◽

Richard G. Finke

Keyword(s):

Phase Transformation ◽

Kinetic Data ◽

Chemical Mechanism ◽

Transformation Kinetic ◽

Phase Transformation Kinetic

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A Test of the Transition-Metal Nanocluster Formation and Stabilization Ability of the Most Common Polymeric Stabilizer, Poly(vinylpyrrolidone), as Well as Four Other Polymeric Protectants†

Langmuir ◽

10.1021/la060934m ◽

2006 ◽

Vol 22 (22) ◽

pp. 9357-9367 ◽

Cited By ~ 31

Author(s):

Lisa Starkey Ott ◽

Brooks J. Hornstein ◽

Richard G. Finke

Keyword(s):

Transition Metal ◽

Polymeric Stabilizer ◽

Metal Nanocluster

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Transition-Metal Nanocluster Size vs Formation Time and the Catalytically Effective Nucleus Number: A Mechanism-Based Treatment

Journal of the American Chemical Society ◽

10.1021/ja8017412 ◽

2008 ◽

Vol 130 (36) ◽

pp. 11959-11969 ◽

Cited By ~ 110

Author(s):

Murielle A. Watzky ◽

Eric E. Finney ◽

Richard G. Finke

Keyword(s):

Transition Metal ◽

Formation Time ◽

Metal Nanocluster

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Transition-Metal Nanocluster Catalysts: Scaled-upSynthesis, Characterization, Storage Conditions, Stability, and Catalytic Activity before and after Storage of Polyoxoanion- and Tetrabutylammonium-Stabilized Ir(0) Nanoclusters

Chemistry of Materials ◽

10.1021/cm020856y ◽

2003 ◽

Vol 15 (4) ◽

pp. 899-909 ◽

Cited By ~ 21

Author(s):

Brooks J. Hornstein ◽

Richard G. Finke

Keyword(s):

Catalytic Activity ◽

Transition Metal ◽

Storage Conditions ◽

Before And After ◽

Metal Nanocluster

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