Electrolyte Dependence of CO2 Electroreduction: Tetraalkylammonium Ions Are Not Electrocatalysts

ACS Catalysis ◽  
2014 ◽  
Vol 5 (2) ◽  
pp. 703-707 ◽  
Author(s):  
Timothy C. Berto ◽  
Linghong Zhang ◽  
Robert J. Hamers ◽  
John F. Berry

1994 ◽  
Vol 59 (8) ◽  
pp. 1738-1744
Author(s):  
Vladislav Holba

The solubilities of tetraalkylammonium dianilinetetraisothiocyanatochromates(III) (alkyl = methyl, ethyl, 1-propyl, and 1-butyl) in water, water - methanol, water - tert-butyl alcohol and water - acetonitrile solutions were measured at 25 °C. The results were used to evaluate the activity coefficients and Gibbs energies of transfer of the saturating salts from water to the mixed systems. The Gibbs energies of transfer of the [Cr(C6H5NH2)2(NCS)4]- ion were obtained by means of known ionic transfer functions for the tetraalkylammonium ions based on the TATB assumption.



2020 ◽  
Vol 4 (7) ◽  
pp. 3726-3731
Author(s):  
Fenghui Ye ◽  
Jinghui Gao ◽  
Yilin Chen ◽  
Yunming Fang

Electroreduction of CO2 into value-added products is a promising technique in which the structure of the catalyst plays a crucial role.



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