Kinetics of the hydrodesulfurization on a cobalt-molybdenum/.gamma.-alumina catalyst. 2. Kinetics of the hydrogenolysis of benzothiophene

1986 ◽  
Vol 25 (3) ◽  
pp. 437-443 ◽  
Author(s):  
Ignace A. Van Parijs ◽  
Lucien H. Hosten ◽  
Gilbert F. Froment
1995 ◽  
Vol 60 (4) ◽  
pp. 568-575
Author(s):  
Karel Sporka ◽  
Jiří Hanika ◽  
Vladimír Jůn

Preparation of skeletal Co-Mo catalysts by controlled impregnation of aluminosilicate skeletons containing deposited gamma-alumina with aqueous solutions of active component precursors has been investigated. The activity of the laboratory catalysts in gas oil hydrodesulfurization has been determined. Kinetics of impregnation of skeletal supports, the effect of their type, and the dependence of catalyst activity on the content of cobalt and molybdenum sulfides are reported. HDS skeletal catalysts prepared were compared with the extruded types. It was found that skeletal HDS catalysts show the higher activity (related to the content of alumina and Co-Mo sulfides) than the extruded ones due to the less significant effect of internal diffusion. However, if the activity is related to the same volume of catalyst bed, the activity of skeletal catalysts is only one fourth of that of the extruded types.


2002 ◽  
Vol 38 (2) ◽  
pp. 139-149 ◽  
Author(s):  
Salvador Ordóñez ◽  
Lisardo Bello ◽  
Herminio Sastre ◽  
Roberto Rosal ◽  
Fernando V. Dı́ez

2010 ◽  
Vol 102 (1) ◽  
pp. 183-194 ◽  
Author(s):  
Yeqiang Chen ◽  
Shenfeng Yuan ◽  
Hong Yin ◽  
Zhirong Chen ◽  
Chunqiang Mao

AIChE Journal ◽  
2006 ◽  
Vol 52 (3) ◽  
pp. 1142-1156 ◽  
Author(s):  
Amitava Sarkar ◽  
Deepyaman Seth ◽  
Flora T. T. Ng ◽  
Garry L. Rempel

1985 ◽  
Vol 24 (3) ◽  
pp. 525-530 ◽  
Author(s):  
Y. S. Bhat ◽  
B. D. Kulkarni ◽  
L. K. Doraiswamy
Keyword(s):  

2009 ◽  
Vol 113 (41) ◽  
pp. 17787-17794 ◽  
Author(s):  
Renchun Yang ◽  
Xiaogang Li ◽  
Junsheng Wu ◽  
Xin Zhang ◽  
Zhihua Zhang

2015 ◽  
Vol 5 (9) ◽  
pp. 4622-4635 ◽  
Author(s):  
B. Rabindran Jermy ◽  
S. Asaoka ◽  
S. Al-Khattaf

Influence of calcination on the binary-metal oxide 30 wt% Bi-20 wt% Ni–O/gamma-Al2O3 catalyst was studied for n-butane oxidative dehydrogenation to 1,3-butadiene.


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