Combination of Metal-Metal Bonding and Antiferromagnetic Exchange Interaction in the d2-d2 Complex [V2O(SPh)4(Me2-bpy)2].cntdot.THF (Me2-bpy = 4,4'-Dimethylbipyridine)

1995 ◽  
Vol 34 (6) ◽  
pp. 1608-1616 ◽  
Author(s):  
Norman S. Dean ◽  
Stuart L. Bartley ◽  
William E. Streib ◽  
Emil B. Lobkovsky ◽  
George Christou
2015 ◽  
Vol 51 (65) ◽  
pp. 12958-12961 ◽  
Author(s):  
Christian Wäckerlin ◽  
Fabio Donati ◽  
Aparajita Singha ◽  
Romana Baltic ◽  
Anne-Christine Uldry ◽  
...  

A record strong antiferromagnetic exchange interaction between an organic magnetic semiconductor and an insulating ferromagnetic oxide is observed.


APL Materials ◽  
2017 ◽  
Vol 5 (12) ◽  
pp. 126105 ◽  
Author(s):  
Liyun Jia ◽  
Jianlei Shen ◽  
Mengmeng Li ◽  
Xi Wang ◽  
Li Ma ◽  
...  

1995 ◽  
Vol 50 (11) ◽  
pp. 1587-1590 ◽  
Author(s):  
Yalcin Elerman ◽  
Mehmet Kabak ◽  
Ingrid Svoboda ◽  
Hartmut Fuess ◽  
Klaus Griesar ◽  
...  

The tetracupferronato-bis(μ-methoxy)-diiron(III) complex has been synthesized in acetonitrile and its crystal structure determined. C26H26N8O10Fe2, monoclinic, space group C2/c, a =18.425(3), b = 12.999(2), c = 15.046(3) Å, β = 124.66(2)°,V = 2964(1) Å3, Z = 4, wR(2) = 0.097 from 1491 reflections (F2). Two iron(III) atoms are at special positions in six-fold coordination, bridged by O with a Fe-O-Fe angle of 102.4(1)° and a distance between two iron(III) centers of 3.075(1) Å. Temperature-dependent magnetic susceptibility measurements reveal a antiferromagnetic exchange interaction (J = -14 cm-1) between the iron(III) centers.


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