Chiroptical properties of trigonal-bipyramidal complexes of copper(II), nickel(II), and cobalt(II) containing an optically active tetraamine

1985 ◽  
Vol 24 (9) ◽  
pp. 1348-1354 ◽  
Author(s):  
Shunji Utsuno ◽  
Hiroshi Miyamae ◽  
Soichiro Horikoshi ◽  
Izumi Endo



2000 ◽  
Vol 33 (9) ◽  
pp. 3237-3243 ◽  
Author(s):  
Ian D. Norris ◽  
Leon A. P. Kane-Maguire ◽  
Gordon G. Wallace




1979 ◽  
Vol 101 (6) ◽  
pp. 1615-1617 ◽  
Author(s):  
John M. Gardlik ◽  
Larry K. Johnson ◽  
Leo A. Paquette ◽  
Barbara A. Solheim ◽  
James P. Springer ◽  
...  






1997 ◽  
Vol 50 (9) ◽  
pp. 939 ◽  
Author(s):  
Fang Chen ◽  
Parveen Akhtar ◽  
Leon A. P. Kane-Maguire ◽  
Gordon G. Wallace

A range of optically active pyrrole monomers have been synthesized in which a chiral sub- stituent is covalently bonded either to the pyrrole N or C3 ring position, namely (–)-(1R)-4-methyl-N-(1-phenylethyl)pyrrole-3-carboxamide, (+)-(1S)-4-methyl-N-(1-phenylethyl)pyrrole-3-carboxamide, (–)-(1R)-4-methyl-N-(1-naphthylethyl)pyrrole-3-carboxamide, (+)-(1S)-4-methyl-N-(1-naphthylethyl)pyrrole-3-carboxamide, (+)-(2S)-2-(1H-pyrrol-1-yl)propionic acid, (+)-(1S)-N-(1-phenyl-ethyl)pyrrole, and (–)-(1R)-N-(1-phenylethyl)pyrrole. Their chiroptical properties have been established by circular dichroism spectroscopy. Electropolymerization of the three N-substituted pyrrole monomers provided films of chiral conducting polymers, whose electrical and spectroscopic properties are described. Although oxidation of the C3 substituted pyrrole monomers was also facile, electrodeposition was poor and films of the associated polymers could not be obtained.



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