Comparison of Metal−Metal Electronic Interactions in an Isomeric Pair of Dinuclear Ruthenium Complexes with Different Bridging Pathways:  Effective Hole Transfer through a Bis-phenolate Bridge

2001 ◽  
Vol 40 (16) ◽  
pp. 4089-4092 ◽  
Author(s):  
Rebecca H. Laye ◽  
Samantha M. Couchman ◽  
Michael D. Ward
Keyword(s):  
Ruthenium Complexes ◽  
Hole Transfer ◽  
Electronic Interactions ◽  
Isomeric Pair ◽  
Metal Metal ◽  
Dinuclear Ruthenium ◽  
Dinuclear Ruthenium Complexes

scholarly journals Dinuclear ruthenium complexes containing a new ditopic phthalazin-bis(triazole) ligand that promotes metal–metal interactions

2014 ◽  
Vol 38 (5) ◽  
pp. 1980-1987 ◽  
Author(s):  
Joan Aguiló ◽  
Atena Naeimi ◽  
Roger Bofill ◽  
Helge Mueller-Bunz ◽  
Antoni Llobet ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Metal Interactions ◽  
Metal Metal ◽  
Triazole Ligand ◽  
Dinuclear Ruthenium ◽  
Dinuclear Ruthenium Complexes

scholarly journals Metal–metal interactions in dinuclear ruthenium complexes containing bridging 4,5-di(2-pyridyl)imidazolates and related ligands

2006 ◽  
pp. 1954-1962 ◽  
Author(s):  
Jonathan W. Slater ◽  
Deanna M. D'Alessandro ◽  
F. Richard Keene ◽  
Peter J. Steel
Keyword(s):  
Ruthenium Complexes ◽  
Metal Interactions ◽  
Metal Metal ◽  
Dinuclear Ruthenium ◽  
Dinuclear Ruthenium Complexes

Noncovalent Trapping and Stabilization of Dinuclear Ruthenium Complexes within a Coordination Cage

2011 ◽  
Vol 133 (32) ◽  
pp. 12445-12447 ◽  
Author(s):  
Shinnosuke Horiuchi ◽  
Takashi Murase ◽  
Makoto Fujita
Keyword(s):  
Ruthenium Complexes ◽  
Dinuclear Ruthenium ◽  
Dinuclear Ruthenium Complexes

Promoting the Activity of Catalysts for the Oxidation of Water with Bridged Dinuclear Ruthenium Complexes

2013 ◽  
Vol 125 (12) ◽  
pp. 3482-3485 ◽  
Author(s):  
Yi Jiang ◽  
Fei Li ◽  
Biaobiao Zhang ◽  
Xiaona Li ◽  
Xiaohong Wang ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Dinuclear Ruthenium ◽  
Dinuclear Ruthenium Complexes

Substitution and redox reactions of mono- and dinuclear ruthenium complexes containing the ligand

2005 ◽  
Vol 358 (6) ◽  
pp. 1798-1806 ◽  
Author(s):  
D. Sellmann ◽  
S.Y. Shaban ◽  
A. Rösler ◽  
F.W. Heinemann
Keyword(s):  
Redox Reactions ◽  
Ruthenium Complexes ◽  
Dinuclear Ruthenium ◽  
Dinuclear Ruthenium Complexes

Rod-like Dinuclear Ruthenium Complexes for Dye-sensitized Photovoltaics

2001 ◽  
Vol 708 ◽  
Author(s):  
Ravi Mosurkal ◽  
Jin-An He ◽  
Jayant Kumar ◽  
Lian Li ◽  
John Walker ◽  
...  
Keyword(s):  
Photovoltaic Cells ◽  
Ruthenium Complexes ◽  
Liquid Electrolyte ◽  
Photovoltaic Properties ◽  
Dye Sensitized ◽  
Dinuclear Ruthenium ◽  
Rigid Rod ◽  
Terpyridine Ligands ◽  
Polynuclear Ruthenium Complexes ◽  
Dinuclear Ruthenium Complexes

ABSTRACTRuthenium complexes with tridentate terpyridine type ligands have many structural advantages over the complexes with bipyridine ligands. Polynuclear ruthenium complexes prepared using these terpyridine ligands bridged with phenylene rings are potential candidates for photosensitization in dye-sensitized photovoltaic cells. In this study, we have carried out synthesis, characterization and theoretical modeling of rigid, rod-like homometallic dinuclear ruthenium complexes using terpyridine and bipyridine ligands. The photophysical and photovoltaic properties have been investigated. These supramolecular dyes are found to be efficient photosensitizers in dye-sensitized photovoltaic cells when a liquid electrolyte is employed.

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