Mixed-Metal Supramolecular Complexes Coupling Phosphine-Containing Ru(II) Light Absorbers to a Reactive Pt(II) through Polyazine Bridging Ligands

2002 ◽  
Vol 41 (9) ◽  
pp. 2598-2607 ◽  
Author(s):  
Shawn Swavey ◽  
Zhenglai Fang ◽  
Karen J. Brewer
Keyword(s):  
Supramolecular Complexes ◽  
Bridging Ligands ◽  
Mixed Metal ◽  
Light Absorbers

Photochemical properties of mixed-metal supramolecular complexes

1994 ◽  
Vol 80 (1-3) ◽  
pp. 315-322 ◽  
Author(s):  
Sharon M. Molnar ◽  
Glen E. Jensen ◽  
Lisa M. Vogler ◽  
Sumner W. Jones ◽  
Leroy Laverman ◽  
...  
Keyword(s):  
Supramolecular Complexes ◽  
Mixed Metal ◽  
Photochemical Properties

Designing mixed-metal supramolecular complexes

2001 ◽  
Author(s):  
Karen J. Brewer ◽  
Shawn Swavey ◽  
Rodd L. Williams ◽  
Zhenglai Fang ◽  
Elizabeth R. Bullock
Keyword(s):  
Supramolecular Complexes ◽  
Mixed Metal

scholarly journals DFT/TD-DFT Framework of Mixed-Metal Complexes with Symmetrical and Unsymmetrical Bridging Ligands—Step-By-Step Investigations: Mononuclear, Dinuclear Homometallic, and Heterometallic for Optoelectronic Applications

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7783
Author(s):  
Dawid Zych
Keyword(s):  
Density Functional Theory ◽  
Dft Calculations ◽  
Metal Complexes ◽  
Density Functional ◽  
Physical Parameters ◽  
Bridging Ligands ◽  
Functional Theory ◽  
Mixed Metal ◽  
Td Dft ◽  
Mixed Metal Complexes

Recently, mono- and dinuclear complexes have been in the interest of scientists due to their potential application in optoelectronics. Herein, progressive theoretical investigations starting from mononuclear followed by homo- and heterometallic dinuclear osmium and/or ruthenium complexes with NCN-cyclometalating bridging ligands substituted by one or two kinds of heteroaryl groups (pyrazol-1-yl and 4-(2,2-dimethylpropyloxy)pyrid-2-yl) providing the short/long axial symmetry or asymmetry are presented. Step-by-step information about the particular part that built the mixed-metal complexes is crucial to understanding their behavior and checking the necessity of their eventual studies. Evaluation by using density functional theory (DFT) calculations allowed gaining information about the frontier orbitals, energy gaps, and physical parameters of complexes and their oxidized forms. Through time-dependent density functional theory (TD-DFT), calculations showed the optical properties, with a particular emphasis on the nature of low-energy bands. The presented results are a clear indication for other scientists in the field of chemistry and materials science.

Design Aspects for the Development of Mixed-Metal Supramolecular Complexes Capable of Visible Light Induced Photocleavage of DNA

2004 ◽  
Vol 43 (1) ◽  
pp. 303-308 ◽  
Author(s):  
Alvin A. Holder ◽  
Shawn Swavey ◽  
Karen J. Brewer
Keyword(s):  
Visible Light ◽  
Supramolecular Complexes ◽  
Mixed Metal
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