Equilibrium Studies in Solution Involving Nickel(II) Complexes of Flexidentate Schiff Base Ligands:  Isolation and Structural Characterization of the Planar Red and Octahedral Green Species Involved in the Equilibrium

2003 ◽  
Vol 42 (25) ◽  
pp. 8439-8445 ◽  
Author(s):  
Suman Mukhopadhyay ◽  
Debdas Mandal ◽  
Dipesh Ghosh ◽  
Israel Goldberg ◽  
Muktimoy Chaudhury
Keyword(s):  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligands ◽  
Equilibrium Studies

scholarly journals SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF PALLADIUM(II) COMPLEXES WITH TETRADENTATE N2O2 AND BIDENTATE NO-DONOR SALICYLALDEHYDE SCHIFF BASE LIGANDS

2018 ◽  
Vol 55 (5B) ◽  
pp. 86
Author(s):  
Lam Quang Hai
Keyword(s):  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligands ◽  
No Donor ◽  
Esi Ms ◽  
Tert Butyl ◽  
High Yields

In this study, a salen-type (R)- and (S)-N-5-tert-butyl-salicylidene-1-phenylethylamine Schiff base ligands and their Pd(II) complexes were synthesized and characterized by ESI-MS, IR and NMR spectroscopies. The ligands were synthesized from the condensation of ethylenediamine with 5-fluoro-salicylaldehyde and (R)- or (S)-1-phenylethylamine with 5-tert-butyl-salicylaldehyde with high yields of 96,3-97.5 %. Their corresponding Pd(II) complexes were formed with yields around 76 %.

Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes

2004 ◽  
Vol 82 (9) ◽  
pp. 1346-1352 ◽  
Author(s):  
Diane A Dickie ◽  
Hanifa Jalali ◽  
Rahul G Samant ◽  
Michael C Jennings ◽  
Jason AC Clyburne
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Structural Characterization ◽  
Condensation Reaction ◽  
Schiff Base Ligands ◽  
X Ray ◽  
X Ray Crystallography ◽  
Aluminum Complexes

2,4,6-Triphenylbenzaldehyde 1 undergoes a condensation reaction with 2-aminophenol to give N-(2′,4′,6′-triphenylbenzylidene)-2-iminophenol (TPIP) 2. The imine 2 can be reduced with NaBH4 in ethanol to form N-(2′,4′,6′-triphenylbenzyl)-2-aminophenol (TPAP) 3. Addition of trimethylaluminum to 2 or 3 results in the formation of the complexes TPIP-AlMe2·AlMe3 (4) or TPAP-AlMe2 (5). Compounds 2, 3, and 4 have been crystallographically characterized.Key words: N,O ligands, aluminum, m-terphenyl, Schiff bases, X-ray crystallography.

scholarly journals Structural Characterization of Heterodinuclear ZnII-LnIII Complexes (Ln = Pr, Nd) with a Ring-Contracted H2valdien-Derived Schiff Base Ligand

2021 ◽  
Author(s):  
Shabana Noor ◽  
Richard Goddard ◽  
Fehmeeda Khatoon ◽  
Sarvendra Kumar ◽  
Rüdiger W. Seidel
Keyword(s):  
Molecular Structure ◽  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligand ◽  
Crystal And Molecular Structure ◽  
X Ray ◽  
X Ray Crystallography ◽  
Imidazoline Ring

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.

Synthesis, crystal structure and magnetic characterization of two Mn(III) chains with Schiff-base ligands

2013 ◽  
Vol 1033 ◽  
pp. 8-13 ◽  
Author(s):  
Cong-Ming Zhang ◽  
Xi-Feng Gao ◽  
Mei Zhu ◽  
Yun-Gai Li ◽  
Qing-Lun Wang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Base Ligands ◽  
Magnetic Characterization
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