SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF PALLADIUM(II) COMPLEXES WITH TETRADENTATE N2O2 AND BIDENTATE NO-DONOR SALICYLALDEHYDE SCHIFF BASE LIGANDS

In this study, a salen-type (R)- and (S)-N-5-tert-butyl-salicylidene-1-phenylethylamine Schiff base ligands and their Pd(II) complexes were synthesized and characterized by ESI-MS, IR and NMR spectroscopies. The ligands were synthesized from the condensation of ethylenediamine with 5-fluoro-salicylaldehyde and (R)- or (S)-1-phenylethylamine with 5-tert-butyl-salicylaldehyde with high yields of 96,3-97.5 %. Their corresponding Pd(II) complexes were formed with yields around 76 %.

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Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes

Canadian Journal of Chemistry ◽

10.1139/v04-110 ◽

2004 ◽

Vol 82 (9) ◽

pp. 1346-1352 ◽

Cited By ~ 5

Author(s):

Diane A Dickie ◽

Hanifa Jalali ◽

Rahul G Samant ◽

Michael C Jennings ◽

Jason AC Clyburne

Keyword(s):

Schiff Base ◽

Schiff Bases ◽

Structural Characterization ◽

Condensation Reaction ◽

Schiff Base Ligands ◽

X Ray ◽

X Ray Crystallography ◽

Aluminum Complexes

2,4,6-Triphenylbenzaldehyde 1 undergoes a condensation reaction with 2-aminophenol to give N-(2′,4′,6′-triphenylbenzylidene)-2-iminophenol (TPIP) 2. The imine 2 can be reduced with NaBH4 in ethanol to form N-(2′,4′,6′-triphenylbenzyl)-2-aminophenol (TPAP) 3. Addition of trimethylaluminum to 2 or 3 results in the formation of the complexes TPIP-AlMe2·AlMe3 (4) or TPAP-AlMe2 (5). Compounds 2, 3, and 4 have been crystallographically characterized.Key words: N,O ligands, aluminum, m-terphenyl, Schiff bases, X-ray crystallography.

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Synthesis and structural characterization of copper(II) and vanadium(V) complexes of pyridyl/pyrimidyl–pyrazole derived Schiff base ligands – Metal specific adjustment of ligand binding mode

Polyhedron ◽

10.1016/j.poly.2008.07.024 ◽

2008 ◽

Vol 27 (15) ◽

pp. 3267-3274 ◽

Cited By ~ 35

Author(s):

Tarak Nath Mandal ◽

Somnath Roy ◽

Anil Kumar Barik ◽

Samik Gupta ◽

Ray J. Butcher ◽

...

Keyword(s):

Schiff Base ◽

Ligand Binding ◽

Structural Characterization ◽

Binding Mode ◽

Schiff Base Ligands

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New triphenyltin(IV) complexes of flexible tripodal Schiff base ligands: X-ray structural characterization of Ph3SnCl.(H3trensal)

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2017.07.020 ◽

2017 ◽

Vol 848 ◽

pp. 10-21 ◽

Cited By ~ 5

Author(s):

Sundeep Kumar ◽

Mala Nath

Keyword(s):

Schiff Base ◽

Structural Characterization ◽

Schiff Base Ligands ◽

X Ray

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Equilibrium Studies in Solution Involving Nickel(II) Complexes of Flexidentate Schiff Base Ligands: Isolation and Structural Characterization of the Planar Red and Octahedral Green Species Involved in the Equilibrium

Inorganic Chemistry ◽

10.1021/ic0346174 ◽

2003 ◽

Vol 42 (25) ◽

pp. 8439-8445 ◽

Cited By ~ 54

Author(s):

Suman Mukhopadhyay ◽

Debdas Mandal ◽

Dipesh Ghosh ◽

Israel Goldberg ◽

Muktimoy Chaudhury

Keyword(s):

Schiff Base ◽

Structural Characterization ◽

Schiff Base Ligands ◽

Equilibrium Studies

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Synthesis and structural characterization of three manganese(III) complexes with N2O2 donor tetradentate Schiff base ligands: Exploration of their catalase mimicking activity

Inorganica Chimica Acta ◽

10.1016/j.ica.2019.05.003 ◽

2019 ◽

Vol 494 ◽

pp. 123-131 ◽

Cited By ~ 1

Author(s):

Ipsita Mondal ◽

Kousik Ghosh ◽

Shouvik Chattopadhyay

Keyword(s):

Schiff Base ◽

Structural Characterization ◽

Schiff Base Ligands ◽

Tetradentate Schiff Base

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Mononuclear manganese(iii) complexes of bidentate NO donor Schiff base ligands: synthesis, structural characterization, magnetic and catecholase studies

RSC Advances ◽

10.1039/c5ra00239g ◽

2015 ◽

Vol 5 (30) ◽

pp. 23855-23864 ◽

Cited By ~ 11

Author(s):

Arpan Dutta ◽

Surajit Biswas ◽

Malay Dolai ◽

Bikash Kumar Shaw ◽

Abhishake Mondal ◽

...

Keyword(s):

Schiff Base ◽

Structural Characterization ◽

Schiff Base Ligands ◽

No Donor

We have synthesized four mononuclear manganese(iii) complexes (1–4) of four closely related bidentate NO donor Schiff-base ligands, out of which three (2–4) were structurally characterized.

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Faculty Opinions recommendation of Biochemical and Structural Characterization of a Schiff Base in the Radical-Mediated Biosynthesis of 4-Demethylwyosine by TYW1.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.733290413.793547302 ◽

2018 ◽

Author(s):

Karen Allen

Keyword(s):

Schiff Base ◽

Structural Characterization

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Structural Characterization of Heterodinuclear ZnII-LnIII Complexes (Ln = Pr, Nd) with a Ring-Contracted H2valdien-Derived Schiff Base Ligand

Journal of Chemical Crystallography ◽

10.1007/s10870-021-00891-4 ◽

2021 ◽

Author(s):

Shabana Noor ◽

Richard Goddard ◽

Fehmeeda Khatoon ◽

Sarvendra Kumar ◽

Rüdiger W. Seidel

Keyword(s):

Molecular Structure ◽

Schiff Base ◽

Structural Characterization ◽

Schiff Base Ligand ◽

Crystal And Molecular Structure ◽

X Ray ◽

X Ray Crystallography ◽

Imidazoline Ring

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.

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