The Far-Infrared Spectra of Metal-Halide Complexes of Pyridine and Related Ligands

1965 ◽  
Vol 4 (3) ◽  
pp. 350-357 ◽  
Author(s):  
Robin J. H. Clark ◽  
Charles S. Williams

1967 ◽  
Vol 23 (11) ◽  
pp. 2701-2704 ◽  
Author(s):  
J. Bradbury ◽  
K.P. Forest ◽  
R.H. Nuttall ◽  
D.W.A. Sharp


Author(s):  
Kirk H. Michaelian ◽  
Kelly L. Akers ◽  
Shuliang L. Zhang ◽  
Shmuel Yariv ◽  
Isaak Lapides


1973 ◽  
Vol 27 (3) ◽  
pp. 213-217 ◽  
Author(s):  
Y. Saito ◽  
C. W. Schläpfer ◽  
M. Cordes ◽  
K. Nakamoto

The far infrared spectra of Ni (pyridine)4X2 and Ni(γ-picoline)4X2 (X = CI, Br and I) have been measured. The Ni-X and Ni-N stretching bands have been assigned based on isotopic shifts due to the 58Ni-62Ni, pyridine-pyridine-d5, and Cl-37Cl substitutions.



1972 ◽  
Vol 6 ◽  
pp. 284-290 ◽  
Author(s):  
C.W. Schläpfer ◽  
Yutaka Saito ◽  
K. Nakamoto


2002 ◽  
Vol 106 (15) ◽  
pp. 3819-3822 ◽  
Author(s):  
Lin Zhang ◽  
Hua Wei ◽  
Yu Zhang ◽  
Zijian Guo ◽  
Longgen Zhu




1972 ◽  
Vol 45 (11) ◽  
pp. 3309-3314 ◽  
Author(s):  
Tomoichi Kamo ◽  
Masao Kimura


1967 ◽  
Vol 45 (24) ◽  
pp. 3187-3192 ◽  
Author(s):  
Arthur J. Carty

Infrared spectra of some triarylphosphine and diphosphine complexes of gallium (III) chloride, bromide, and iodide have been recorded in the range 600–200 cm−1 and assignments of gallium–halogen stretching vibrations made. The number and frequencies of the ν (Ga–X) vibrations are consistent with monomeric structures for the triarylphosphine complexes in the solid state. Possible structures for the diphosphine complexes are discussed.



1974 ◽  
Vol 52 (11) ◽  
pp. 2021-2028 ◽  
Author(s):  
C. Preti ◽  
G. Tosi ◽  
D. De Filippo ◽  
G. Verani

Cobalt(II) and nickel(II) halide complexes with thiomorpholin-3-thione and thiazolidine-2-selenone have been prepared. Infrared and far infrared spectra, electronic spectral studies, and magnetic susceptibility measurements indicate that the cobalt derivatives are tetrahedral in structure, nickel chloro- and bromo-thiomorpholin-3-thione derivatives are octahedral while [Nits2I2] and all nickel thiazolidine-2-selenone complexes have a pseudo-tetrahedral symmetry. The probable site of bonding in the ligands is nitrogen in all the complexes studied here, except the nickel derivatives of thiazolidine-2-selenone. These results are confirmed by n.m.r. measurements. Spectroscopic parameters for the complexes have been calculated and compared against similar chromophores containing MN2X2 and MS2X2 chromophores.



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