Preparation of B-methyl derivatives of dicarbahexaborane(8). The correlation of proton nuclear magnetic resonance chemical shift measurements in dicarbahexaborane(8) derivatives by employing "ring-current" contributions

1968 ◽  
Vol 7 (9) ◽  
pp. 1754-1757 ◽  
Author(s):  
Thomas Onak ◽  
Dennis Marynick ◽  
Peter Mattschei ◽  
Gary Dunks

1974 ◽  
Vol 52 (18) ◽  
pp. 3196-3200 ◽  
Author(s):  
Gerald W. Buchanan ◽  
Giorgio Montaudo ◽  
Paolo Finocchiaro

Carbon-13 n.m.r. chemical shifts are reported for diphenylmethane and nine methylated derivatives. Results are compared with those for related methylbenzenes. In the case of tri-ortho-substituted materials the predominance of a perpendicular conformation is suggested. Ring current calculations show that in contrast to the 1H chemical shift interpretations, the 13C shielding trends cannot originate primarily from anisotropic effects.



1965 ◽  
Vol 87 (24) ◽  
pp. 5575-5582 ◽  
Author(s):  
Edwin D. Becker ◽  
H. Todd Miles ◽  
Robert B. Bradley


1987 ◽  
Vol 65 (3) ◽  
pp. 666-669 ◽  
Author(s):  
R. D. Dawe ◽  
J. L. C. Wright

Carbon and proton assignments for muricin aglycone (5) and a number of related pregnenes, carried out with the aid of two-dimensional homo- and heteronuclear chemical shift correlation experiments, have resulted in previously reported carbon assignments for the aglycone being revised. An improved route to muricin aglycone is also reported.



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