Synthesis and properties of cobalt and nickel complexes with the tripod ligand tris(2-diphenylarsinoethyl)amine. Structural characterization of a .sigma.-phenyl complex of nickel(II) with the same ligand

1976 ◽  
Vol 15 (2) ◽  
pp. 325-329 ◽  
Author(s):  
L. Sacconi ◽  
P. Dapporto ◽  
P. Stoppioni
Keyword(s):  
Structural Characterization ◽  
Nickel Complexes ◽  
Cobalt And Nickel

Progress in preparation and characterization of silylene iron, cobalt and nickel complexes

2021 ◽  
Author(s):  
Wenjing Yang ◽  
Yanhong Dong ◽  
Hongjian Sun ◽  
Xiaoyan Li
Keyword(s):  
Nickel Complexes ◽  
Electron Cloud ◽  
Synthesis And Characterization ◽  
Iron Cobalt ◽  
Cloud Density ◽  
Cobalt And Nickel

The synthesis and characterization of Fe, Co and Ni complexes supported by silylene ligands in recent ten years are summarized. Due to the decrease of electron cloud density on Si...

Valence Isomerization. Synthesis and Characterization of Cobalt and Nickel Complexes with Non-Innocent N2S2Ligand

1997 ◽  
Vol 70 (7) ◽  
pp. 1599-1606 ◽  
Author(s):  
Tatsuya Kawamoto ◽  
Hiro Kuma ◽  
Yoshihiko Kushi
Keyword(s):  
Nickel Complexes ◽  
Synthesis And Characterization ◽  
Valence Isomerization ◽  
Cobalt And Nickel

Synthesis and characterization of chiral trinuclear cobalt and nickel complexes supported by binaphthol-derived bis(salicylaldimine) ligands

2013 ◽  
Vol 66 (18) ◽  
pp. 3182-3192 ◽  
Author(s):  
Lei Zhang ◽  
Wei Gao ◽  
Qiaolin Wu ◽  
Qing Su ◽  
Jingshun Zhang ◽  
...  
Keyword(s):  
Nickel Complexes ◽  
Synthesis And Characterization ◽  
Cobalt And Nickel

scholarly journals Chances and Limits of the Coordination Chemistry with Bis(benzene-l,2-dithiolato) Ligands

2005 ◽  
Vol 3 (1-2) ◽  
pp. 69-80 ◽  
Author(s):  
Wolfram W. Seidel ◽  
F. Ekkehardt Hahn
Keyword(s):  
Coordination Chemistry ◽  
Structural Characterization ◽  
Building Blocks ◽  
Dinuclear Complexes ◽  
Chelate Complexes ◽  
Helical Structures ◽  
Square Planar ◽  
Supramolecular Coordination ◽  
Cobalt And Nickel

The incorporation of benzene-l,2-dithiolato building blocks into supramolecular coordination assemblies is the main objective of the investigations described here. Special interest is directed towards dinuclear complexes with bis(benzene-l,2-dithiolato) ligands, which might be able to form helical structures. Bis(benzene-l,2-dithiolato) ligands are accessible byortho-functionalization and subsequent linkage of two benzene-l,2-dithiol units. The preparation of well defined complexes of titanium, cobalt and nickel with bis(benzene-l,2-dithiolato) ligands requires strictly thermodynamic equilibration conditions. In that case the size and shape of the ligand backbone determine if dinuclear double-stranded or mononuclear chelate complexes are obtained. The dinuclear double-stranded complexes with Ni(II) and Ni(III) are characterized by a coplanar non-helical arrangement of the square-planar bis(benzene-l,2-dithiolato)nickelate moieties. The complete structural characterization of the series[M(C6H4S2-1,2)3]n-(n = 0, 1, 2) for molybdenum and tungsten indicates an interesting coordination chemistry of dinuclear triple-stranded complexes.

Synthesis and Structural Characterization of Nickel Complexes Possessing P-Stereogenic Pincer Scaffolds and Their Application in Asymmetric Aza-Michael Reactions

2015 ◽  
Vol 34 (7) ◽  
pp. 1228-1237 ◽  
Author(s):  
Zehua Yang ◽  
Delong Liu ◽  
Yangang Liu ◽  
Masashi Sugiya ◽  
Tsuneo Imamoto ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Nickel Complexes ◽  
Michael Reactions

scholarly journals SYNTHESIS AND CHARACTERIZATION OF SOME HYDRAZINEDERIVATIVES WITH Α, Β UNSATURATED ACIDS

2015 ◽  
Vol 2 (2) ◽  
pp. 16-22
Author(s):  
Manimekalai R ◽  
Kalpanadevi K ◽  
Anjutha Prabha N ◽  
Raina O
Keyword(s):  
Metal Ion ◽  
Nickel Complexes ◽  
Synthesis And Characterization ◽  
Metal Carboxylate ◽  
X Ray Diffraction ◽  
X Ray ◽  
Diffraction Patterns ◽  
Dta Studies ◽  
Cobalt And Nickel

Metal cinnamate monohydrazinates of the formula M(cin)2N2H4, where M= Co or Zn, nickel crotante monohydrazinate monohydrate Ni(crot)2N2H4.H2O, metal cinnamate and crotonate dihydrazinates M(cin)2(N2H4)2 Where M = Co, Ni, Zn or Cd , M(crot)2(N2H4)2 Where M = Co or Ni and cadmium crotante dihydrazinate monohydrate Cd(crot)2(N2H4)2.H2O have been prepared and characterized by spectral, thermal and X-ray diffraction studies. Electronic spectra indicate that the cobalt and nickel complexes are high-spin octahedral complexes. The IR data show that the binding of hydrazine and the unsaturated carboxylate anion to the metal ion is bidentate. TG-DTA studies show that metal complexes undergo decomposition through metal carboxylate intermediate to give respective metal oxide as the final product. Xray powder diffraction patterns of the complexes indicate isomorphism among them.

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