MOFs-Derived Zn-Based Catalysts in Acetylene Acetoxylation

Metal–organic frameworks (MOFs)-derived materials with a large specific surface area and rich pore structures are favorable for catalytic performance. In this work, MOFs are successfully prepared. Through pyrolysis of MOFs under nitrogen gas, zinc-based catalysts with different active sites for acetylene acetoxylation are obtained. The influence of the oxygen atom, nitrogen atom, and coexistence of oxygen and nitrogen atoms on the structure and catalytic performance of MOFs-derived catalysts was investigated. According to the results, the catalysts with different catalytic activity are Zn-O-C (33%), Zn-O/N-C (27%), and Zn-N-C (12%). From the measurements of X-ray photoelectron spectroscopy (XPS), it can be confirmed that the formation of different active sites affects the electron cloud density of zinc. The electron cloud density of zinc affects the ability to attract CH3COOH, which makes catalysts different in terms of catalytic activity.

Performance Study of Zn-Co-Ni/AC Catalyst in Acetylene Acetylation

Zinc acetate (Zn(OAc)2) loaded on activated carbon (AC) is the most commonly used catalyst for the industrial synthesis of vinyl acetate (VAc) using the acetylene method. The aim of this study is to optimize the Zn(OAc)2/AC catalyst by adding co-catalysts to improve its activity and stability. Ternary catalysts were synthesized by adding Co and Ni to the Zn(OAc)2/AC catalyst (Zn-Co-Ni/AC). Due to the strong synergistic effect among promoter Co, Ni, and the active component of Zn(OAc)2, the resulting catalyst is capable to absorb more acetic acid and less acetylene. The stability and activity of Zn-Co-Ni/AC catalyst have been improved through electron transfer to alter the electron cloud density around the Zn element. Under the same reaction conditions, the activity of Zn-Co-Ni/AC catalyst was enhanced by 83% compared to that of Zn(OAc)2/AC, and the activity was still as high as 30.1% after 120 h of testing.

Distributed MEMS Sensors using Plasmonic Antenna Array Embedded Sagnac Interferometer

A micro Sagnac interferometer is proposed for electron cloud distributed sensors formed by an integrated (micro-electro-mechanical systems) MEMS resonator structure. The Sagnac interferometer consists of four microring probes integrated into a Sagnac loop. Each of the microring probes is embedded with the silver bars to form the plasmonic wave oscillation. The polarized light of 1.50µm wavelength is input into the interferometer, which is polarized randomly into upstream and downstream directions. The polarization outputs can be controlled by the space-time input at the Sagnac port. Electrons are trapped and oscillated by the whispering gallery modes (WGMs), where the plasmonic antennas are established and applied for wireless fidelity (WiFi) and light fidelity (LiFi) sensing probes, respectively. Four antenna gains are 2.59dB, 0.93dB, 1.75dB, and 1.16dB, respectively. In manipulation, the sensing probe electron densities are changed by input source power variation. When the electron cloud is excited by the microscopic medium, where the change in electron density is obtained and reflected to the required parameters. Such a system is a novel device that can be applied for brain-device interfering with the dual-mode sensing probes. The obtained WGM sensors are 1.35µm-2, 0.90µm-2, 0.97µm-2 and, 0.81µm-2, respectively. The WGMs behave as a four-point probe for the electron cloud distributed sensors, where the electron cloud sensitivities of 2.31prads-1mm3 (electrons)-1, 2.27prads-1mm3 (electrons)-1, 2.22prads-1mm3(electrons)-1, 2.38prads-1mm3(electrons)-1 are obtained, respectively.

3D-Fringe Pattern Coding and Recognition Using Plasmonic Sensing Circuit

3D interference fringe pattern recognition using a plasmonic sensing circuit is proposed. The plasmonic sensing in the form of a panda ring comprises of an embedded gold grating at the microring center. WGM (whispering gallery mode) is observed at the microring center with suitable parameters. The dark soliton of 1.50µm wavelength excites the gold grating which leads to electron cloud oscillation and forms the electron densities where the trapped electrons inside the silicon microring are transported via wireless connection using WGM and cable connection. The spin-down |↓〉(|1〉) and spin-up |↑〉(|0〉) result from the electron cloud oscillation. By using the changes in gold lengths, the excited electron pattern recognition can be manipulated, where the values "0 and "1"' are useful for pattern recognition. The fringe patterns of the plasmonic interferometric sensor are recorded, which means that the novel 3D pattern recognition can be possibly implemented and used in many applications. Therefore, the plasmonic sensing circuit can be used to form the quantum code, quantum encryption, quantum sensor, and pattern recognition.