Low-temperature electrochemical studies of unstable species. Pentacarbonylhalochromium(I) system

1976 ◽  
Vol 15 (2) ◽  
pp. 446-448 ◽  
Author(s):  
A. M. Bond ◽  
R. Colton
2020 ◽  
Vol 155 ◽  
pp. 106416 ◽  
Author(s):  
Wei-min Zeng ◽  
Yu-ping Peng ◽  
Tang-jian Peng ◽  
Mei-hua Nan ◽  
Miao Chen ◽  
...  

2012 ◽  
Vol 584 ◽  
pp. 386-390
Author(s):  
R. Prabu ◽  
L. Vijayalakshmi ◽  
V. Narayanan

A new phenoxo-bridged Tet-a based binuclear manganese(III) complexes were synthesized by the Schiff base condensation reaction of the compound 1,8–[bis(3-formyl-2-hydroxy-5-methyl)benzyl] -5,5,7,12,12,14- hexamethyl -l,4,8,11-tetraazacyclotetradecane (PC–a) and 1,8– [bis(3-formyl-2-hydroxy-5-bromo)benzyl]- 5,5,7,12,12,14-hexamethyl-l,4,8,11-tetraazacyclotetradecane (PC–b) with triethylenetetramine and manganese(II) perchlorate hexahydrate. Their synthesized complexes were confirmed by analytical and spectral analysis. The phenolate oxygen atom is acting as bridge between two unsymmetrically coordinated Mn atoms. Electrochemical studies of the complexes reveal that all the redox processes are irreversible in nature. Low temperature magnetic study shows that the complexes exhibit antiferromagnetic exchange interaction between the two metal ions. The spectral and magnetic behavior of the complexes is discussed.


2009 ◽  
Vol 54 (16) ◽  
pp. 4079-4083 ◽  
Author(s):  
Yuxi Zhang ◽  
Honghe Zheng ◽  
Gao Liu ◽  
Vince Battaglia

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