Redox reactivity of transition-metal phthalocyanines: ligand radical formation vs. metal center oxidation

1985 ◽  
Vol 89 (18) ◽  
pp. 3890-3894 ◽  
Author(s):  
D. K. Geiger ◽  
G. Ferraudi ◽  
K. Madden ◽  
J. Granifo ◽  
D. P. Rillema
Keyword(s):  
Transition Metal ◽  
Metal Center ◽  
Radical Formation ◽  
Metal Phthalocyanines ◽  
Redox Reactivity

Some Problems in the Oxidative Addition and Binding of an Ethylene to a Transition Metal Center.

1987 ◽  
Vol 6 (4) ◽  
pp. 902-902
Author(s):  
Jerome Silestre ◽  
Maria Calhorda ◽  
Roald Hoffman ◽  
Page Stoutland ◽  
Robert Bergman
Keyword(s):  
Transition Metal ◽  
Oxidative Addition ◽  
Metal Center

The First Coordination of an (α-Diazo)phosphine to a Transition-Metal Center

2003 ◽  
Vol 22 (7) ◽  
pp. 1358-1360 ◽  
Author(s):  
Emmanuelle Despagnet-Ayoub ◽  
Heinz Gornitzka ◽  
John Fawcett ◽  
Philip W. Dyer ◽  
Didier Bourissou ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Center

Reversible Electrochromism in the Thin Films of Single-Transition Metal Phthalocyanines

1993 ◽  
Vol 22 (8) ◽  
pp. 1299-1302 ◽  
Author(s):  
Naoki Toshima ◽  
Shin-ichi Kawamura ◽  
Tsuyoshi Tominaga
Keyword(s):  
Thin Films ◽  
Transition Metal ◽  
Metal Phthalocyanines ◽  
Single Transition

Transition Metal Phthalocyanines as Nitrogen Oxydes Sensors

2021 ◽  
pp. 1-20
Author(s):  
Anna Maria Paoletti ◽  
Giovanna Pennesi ◽  
Gentilina Rossi ◽  
Amanda Generosi ◽  
Barbara Paci ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Phthalocyanines

Ligand Effects on the Linear Response Hubbard U: The Case of Transition Metal Phthalocyanines

2019 ◽  
Vol 123 (14) ◽  
pp. 3214-3222
Author(s):  
Iulia Emilia Brumboiu ◽  
Soumyajyoti Haldar ◽  
Johann Lüder ◽  
Olle Eriksson ◽  
Heike C. Herper ◽  
...  
Keyword(s):  
Transition Metal ◽  
Linear Response ◽  
Metal Phthalocyanines ◽  
Ligand Effects ◽  
Hubbard U

Übergangsmetallkomplexe mit Schwefelliganden, LXV. Diastereospezifische Alkylierung von [Mo(NO)2(′S2′)2]2- zu chiralen [Mo(NO)2(′RS4')]-Komplexen mit chirotopen und prostereogenen Mo-Zentren / Transition Metal Complexes with Sulfur Ligands, LXV. Diastereospecific Alkylation of [Mo(NO)2(′S2')2]2- to Chiral [Mo(NO)2(′RS4')] Complexes with Chirotopic and Prostereogenic Mo-Centers

1991 ◽  
Vol 46 (10) ◽  
pp. 1343-1348 ◽  
Author(s):  
Dieter Sellmann ◽  
Franz Grasser ◽  
Falk Knoch ◽  
Matthias Moll
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Parent Compound ◽  
Metal Center ◽  
Chiral Complexes ◽  
Metal Centers ◽  
Electronic Character

In order to investigate how chirotopicity and stereogenicity of metal centers influence the enantioselectivity of metal centered reactions the stereogenic properties of metal centers in chiral complexes have to be varied without changing their electronic character. Diastereospecific alkylation of [Mo(NO)2(′S2′ )2]2- by racemic 1,2-dibromopropane and 1,2-dibromobutane yields the title complexes [Mo(NO)2(′MeS4′ )] and [Mo(NO)2(′EtS4′)] that differ from the parent compound [Mo(NO)2('S4′)] with respect to the stereogenicity of the metal center and allow future investigations of the question raised above.

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