Tunnel effects in hydrogen-atom-transfer reactions as studied by the temperature dependence of the hydrogen deuterium kinetic isotope effects

Noboru. Fujisaki; Amanz. Ruf; Tino. Gaeumann

doi:10.1021/j100290a062

Tunnel effects in hydrogen-atom-transfer reactions as studied by the temperature dependence of the hydrogen deuterium kinetic isotope effects

The Journal of Physical Chemistry ◽

10.1021/j100290a062 ◽

1987 ◽

Vol 91 (6) ◽

pp. 1602-1606

Author(s):

Noboru. Fujisaki ◽

Amanz. Ruf ◽

Tino. Gaeumann

Keyword(s):

Hydrogen Atom ◽

Temperature Dependence ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Hydrogen Atom Transfer ◽

Transfer Reactions ◽

Atom Transfer ◽

Kinetic Isotope ◽

Hydrogen Deuterium ◽

Tunnel Effects

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Ab initio predictions and experimental confirmation of large tunneling contributions to rate constants and kinetic isotope effects for hydrogen atom transfer reactions

Journal of the American Chemical Society ◽

10.1021/ja00272a061 ◽

1986 ◽

Vol 108 (12) ◽

pp. 3515-3516 ◽

Cited By ~ 51

Author(s):

Bruce C. Garrett ◽

Donald G. Truhlar ◽

Joel M. Bowman ◽

Albert F. Wagner ◽

Daniel. Robie ◽

...

Keyword(s):

Hydrogen Atom ◽

Ab Initio ◽

Rate Constants ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Hydrogen Atom Transfer ◽

Experimental Confirmation ◽

Transfer Reactions ◽

Atom Transfer ◽

Kinetic Isotope

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ChemInform Abstract: Kinetic Isotope Effects in Hydrogen Atom Transfer Reactions between Benzylic Carbons.

Chemischer Informationsdienst ◽

10.1002/chin.198625095 ◽

1986 ◽

Vol 17 (25) ◽

Author(s):

B. C. BOCKRATH ◽

E. W. BITTNER ◽

T. C. MARECIC

Keyword(s):

Hydrogen Atom ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Hydrogen Atom Transfer ◽

Transfer Reactions ◽

Atom Transfer ◽

Kinetic Isotope ◽

Atom Transfer Reactions

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Kinetic isotope effects in hydrogen atom transfer reactions between benzylic carbons

The Journal of Organic Chemistry ◽

10.1021/jo00351a003 ◽

1986 ◽

Vol 51 (1) ◽

pp. 15-19 ◽

Cited By ~ 4

Author(s):

Bradley C. Bockrath ◽

Edward W. Bittner ◽

Thomas C. Marecic

Keyword(s):

Hydrogen Atom ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Hydrogen Atom Transfer ◽

Transfer Reactions ◽

Atom Transfer ◽

Kinetic Isotope ◽

Atom Transfer Reactions

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ChemInform Abstract: Ab initio Predictions and Experimental Confirmation of Large Tunneling Contributions to Rate Constants and Kinetic Isotope Effects for Hydrogen Atom Transfer Reactions.

Chemischer Informationsdienst ◽

10.1002/chin.198639023 ◽

1986 ◽

Vol 17 (39) ◽

Author(s):

B. C. GARRETT ◽

D. G. TRUHLAR ◽

J. M. BOWMAN ◽

A. F. WAGNER ◽

D. ROBIE ◽

...

Keyword(s):

Hydrogen Atom ◽

Ab Initio ◽

Rate Constants ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Hydrogen Atom Transfer ◽

Experimental Confirmation ◽

Transfer Reactions ◽

Atom Transfer ◽

Kinetic Isotope

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Substituent Effects on Temperature Dependence of Kinetic Isotope Effects in Hydride-Transfer Reactions of NADH/NAD+ Analogues in Solution: Reaction Center Rigidity Is the Key

Organic Letters ◽

10.1021/acs.orglett.0c02049 ◽

2020 ◽

Vol 22 (15) ◽

pp. 5963-5967

Author(s):

Peter Maness ◽

Shailendra Koirala ◽

Pratichhya Adhikari ◽

Nasim Salimraftar ◽

Yun Lu

Keyword(s):

Temperature Dependence ◽

Reaction Center ◽

Isotope Effects ◽

Substituent Effects ◽

Hydride Transfer ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Solution Reaction ◽

Hydride Transfer Reactions

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ChemInform Abstract: Hydrogen Atom Transfer Reactions: The Nature of the Transition State As Delineated from the Temperature Dependence of the Primary KlE

Chemischer Informationsdienst ◽

10.1002/chin.198404105 ◽

1984 ◽

Vol 15 (4) ◽

Author(s):

H. L. STRONG ◽

M. L. BROWNAWELL ◽

J. JUN. SAN FILIPPO

Keyword(s):

Hydrogen Atom ◽

Transition State ◽

Temperature Dependence ◽

Hydrogen Atom Transfer ◽

Transfer Reactions ◽

Atom Transfer ◽

Atom Transfer Reactions

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Temperature Dependence of Kinetic Isotope Effects in Gas‐Phase Reactions. II. The Hydrogen‐Atom–Formaldehyde Reaction

The Journal of Chemical Physics ◽

10.1063/1.1670055 ◽

1968 ◽

Vol 49 (12) ◽

pp. 5345-5349 ◽

Cited By ~ 3

Author(s):

Digby D. Macdonald ◽

E. Tschuikow‐Roux

Keyword(s):

Hydrogen Atom ◽

Temperature Dependence ◽

Gas Phase ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Gas Phase Reactions ◽

Kinetic Isotope

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Solvent effects on the temperature dependence of the primary kinetic isotope effects for hydride transfer reactions in solution

10.1021/scimeetings.0c05537 ◽

2020 ◽

Author(s):

Pratichhya Adhikari ◽

Shailendra Koirala

Keyword(s):

Temperature Dependence ◽

Solvent Effects ◽

Isotope Effects ◽

Hydride Transfer ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Hydride Transfer Reactions

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Hydrogen atom transfer reactions: the nature of the transition state as delineated from the temperature dependence of the primary KIE

Journal of the American Chemical Society ◽

10.1021/ja00359a048 ◽

1983 ◽

Vol 105 (21) ◽

pp. 6526-6528 ◽

Cited By ~ 10

Author(s):

Henry L. Strong ◽

Marilyn L. Brownawell ◽

Joseph San Filippo

Keyword(s):

Hydrogen Atom ◽

Transition State ◽

Temperature Dependence ◽

Hydrogen Atom Transfer ◽

Transfer Reactions ◽

Atom Transfer ◽

Atom Transfer Reactions

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Additions and Corrections - Hydrogen Atom Transfer Reactions: The Nature of the Transition State As Delineated from the Temperature Dependence of the Primary KIE

Journal of the American Chemical Society ◽

10.1021/ja00330a601 ◽

1984 ◽

Vol 106 (18) ◽

pp. 5388-5388

Author(s):

Henry Strong ◽

Marilyn Brownawell ◽

Joseph San Filippo,Jr.

Keyword(s):

Hydrogen Atom ◽

Transition State ◽

Temperature Dependence ◽

Hydrogen Atom Transfer ◽

Transfer Reactions ◽

Atom Transfer ◽

Atom Transfer Reactions

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