Standard potentials of the silver-silver bromide electrode in propylene glycol and the silver-silver iodide electrode in ethylene and propylene glycols at different temperatures and related thermodynamic quantities

1970 ◽  
Vol 74 (13) ◽  
pp. 2625-2632 ◽  
Author(s):  
Kiron K. Kundu ◽  
Debabrata Jana ◽  
Mihir N. Das
Keyword(s):  
Propylene Glycol ◽  
Silver Iodide ◽  
Silver Bromide ◽  
Thermodynamic Quantities ◽  
Different Temperatures ◽  
Silver Silver

Behaviour of the silver-silver bromide and the silver-silver iodide electrodes in formamide at different temperatures

1975 ◽  
Vol 28 (8) ◽  
pp. 1657 ◽  
Author(s):  
UN Dash ◽  
B Nayak
Keyword(s):  
Silver Iodide ◽  
Silver Bromide ◽  
Thermodynamic Quantities ◽  
Standard Potential ◽  
Different Temperatures ◽  
Silver Silver ◽  
Good Agreement

From the e.m.f. measurements of the buffered cells of the type ��������������������� Pt, H2|HOAc(m1), KOAc(m2), KX(m3)|AgX-Ag the standard potentials of the Ag-AgX electrodes have been determined, in formamide, at nine different temperatures in the range 5-45�. The standard potentials of the Ag-AgX electrodes obtained at 25� are in good agreement with those obtained from the study of the cells ������������������ Ag-AgX|KX(m3), KOAc(m2), HOAc(m1), QH2-Q|Pt at 25�, where X is Br or I. The cell �������������������������Pt,H2|HBr(m)|AgBr-Ag has been further studied in this solvent at 25� with a view to having an independent check on these buffered cells for the standard potential of the Ag-AgBr electrode. The standard thermodynamic quantities (ΔG�, ΔH�, and ΔS�) for the corresponding cell reactions have been calculated from the e.m.f. data over the range, 5-45�.

Standard Potentials of the Silver-Silver Bromide Electrode and Related Thermodynamic Quantities in Propylene Glycol + Water Solvent Mixtures

1983 ◽  
Vol 134 (2) ◽  
pp. 215-226 ◽  
Author(s):  
Mahmoud M. Elsemongy ◽  
Ahmed A. Abdel-Khalek ◽  
Mohamed A. Hussein
Keyword(s):  
Propylene Glycol ◽  
Silver Bromide ◽  
Solvent Mixtures ◽  
Thermodynamic Quantities ◽  
Water Solvent ◽  
Silver Silver
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