On the Theory of Oxidation-Reduction Reactions Involving Election Transfer V. Comparison and Properties of Electrochemical and Chemical Rate Constants - Correction

1963 ◽  
Vol 67 (12) ◽  
pp. 2889-2889 ◽  
Author(s):  
R Marcus
Keyword(s):  
Rate Constants ◽  
Reduction Reactions ◽  
Oxidation Reduction ◽  
Chemical Rate

Oxidation-Reduction Reactions

2007 ◽  
Author(s):  
Robert B. Jordan
Keyword(s):  
Oxidation State ◽  
Rate Constants ◽  
Theoretical Basis ◽  
Reducing Agent ◽  
Oxidizing Agent ◽  
Substitution Reactions ◽  
Reduction Reactions ◽  
Oxidation Reduction ◽  
Inorganic Reactions ◽  
Reaction Stoichiometry

For most purposes, inorganic reactions can be classified as either substitution reactions or oxidation-reduction reactions. The latter involve the transfer of at least one electron from the reducing agent to the oxidizing agent. Such reactions are widely used in analytical procedures and are important in many biological processes. One of the mechanistic types in this area is unique in having a fairly simple theoretical basis for predicting rate constants in solution from measurable input parameters. Oxidation-reduction reactions have been classified in two general ways; the first, historically, is by stoichiometry and the second is by mechanism. The Stoichiometric classification only requires a knowledge of the reaction stoichiometry but has limited kinetic applicability. The change in oxidation state of the reducing agent is the same as the change in oxidation state of the oxidizing agent.

Feedback Controlled Chemical Reactor with Feed of Two Reaction Components with Spectrophotometric Indication

1994 ◽  
Vol 59 (3) ◽  
pp. 549-557
Author(s):  
František Skopal ◽  
Václav Dušek
Keyword(s):  
Sulfuric Acid ◽  
Negative Feedback ◽  
Chemical Reactor ◽  
Reduction Reactions ◽  
Oxidation Reduction

Theoretical relationships and simplifying conditions have been derived for the feed of two reaction components into a nonisochoric reactor with ideal stirring. The feed of reaction components is controlled by the negative feedback at a constant absorbance of the reaction mixture. The theoretical relationships have been verified using model 2. order oxidation-reduction reactions of Ce(IV)/V(IV) and Fe(III)/V(III) in 1 M sulfuric acid at 20 °C.

Volumetric studies in oxidation-reduction reactions

1958 ◽  
Vol 19 ◽  
pp. 10-11 ◽  
Author(s):  
Balwant Singh ◽  
Sardul Singh
Keyword(s):  
Reduction Reactions ◽  
Oxidation Reduction

Interflavin oxidation-reduction reactions between pig kidney general acyl-CoA dehydrogenase and electron-transferring flavoprotein

Biochemistry ◽  
1985 ◽  
Vol 24 (24) ◽  
pp. 6830-6839 ◽  
Author(s):  
Robert J. Gorelick ◽  
Lawrence M. Schopfer ◽  
David P. Ballou ◽  
Vincent Massey ◽  
Colin Thorpe
Keyword(s):  
Reduction Reactions ◽  
Pig Kidney ◽  
Oxidation Reduction ◽  
Electron Transferring Flavoprotein
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