Kinetics of heterogeneous catalytic electrode reactions. II. Charge-transfer kinetics

1969 ◽  
Vol 73 (12) ◽  
pp. 4102-4110 ◽  
Author(s):  
J. D. E. McIntyre
Keyword(s):  
Charge Transfer ◽  
Heterogeneous Catalytic ◽  
Electrode Reactions ◽  
Kinetics Of

Influence of Second Coordination Sphere on the Kinetics of Electrode Reactions in Molten Salts

2002 ◽  
Vol 57 (1-2) ◽  
pp. 85-88
Author(s):  
S. A. Kuznetsov ◽  
M. Gaune-Escarda
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Coordination Sphere ◽  
Diffusion Coefficients ◽  
Redox Reaction ◽  
Alkali Halide ◽  
Molten Salts ◽  
Electrode Reactions ◽  
Second Coordination Sphere ◽  
Kinetics Of

The influence of the second coordination sphere on die electroreduction of hafnium complexes to hafnium metal and the redox reaction Eu(III)+e-⇔ Eu(II) in alkali halide melts was studied. It is shown that die large caesium cations in the melt reduce the transfer and the diffusion coefficients as well as the heterogeneous rate constants for charge transfer of harnitcn complexes. The standard rare constants for the europium redox reaction increase when going from NaCl-KCl to CsCl. The different influence of die second coordination sphere on the electrode reactions is explained by different limitation stages for electron transfer

Time-Resolved Kinetics of Electrode Reactions

2019 ◽  
Vol 1 (6) ◽  
pp. 3-15
Author(s):  
Eliezer Gileadi
Keyword(s):  
Time Resolved ◽  
Electrode Reactions ◽  
Kinetics Of
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