Electron affinities and the electron-capture method for aromatic hydrocarbons

The electron capture method was applied to protoporphyrin IX and meso- porphyrin IX dimethyl esters, metal-free phthalocyanine, chlorophyll, riboflavine, nicotinamide, tetracene, and pentacene. The energy quantities obtained correlated with calculated energies of the lowest empty molecular orbitals of these molecules.

Download Full-text

ChemInform Abstract: Electron Affinities of Aromatic Hydrocarbons. Their Radical Anions and Dianions

ChemInform ◽

10.1002/chin.198840341 ◽

1988 ◽

Vol 19 (40) ◽

Author(s):

M. SZWARC

Keyword(s):

Aromatic Hydrocarbons ◽

Radical Anions ◽

Electron Affinities

Download Full-text

Potential Method for the Determination of Electron Affinities of Molecules: Application to Some Aromatic Hydrocarbons

Journal of the American Chemical Society ◽

10.1021/ja00881a014 ◽

1962 ◽

Vol 84 (22) ◽

pp. 4263-4266 ◽

Cited By ~ 97

Author(s):

W. E. Wentworth ◽

Ralph S. Becker

Keyword(s):

Aromatic Hydrocarbons ◽

Potential Method ◽

Electron Affinities

Download Full-text

Gas phase adiabatic electron affinities of cyclopenta-fused polycyclic aromatic hydrocarbons

Chemical Physics Letters ◽

10.1016/j.cplett.2008.01.065 ◽

2008 ◽

Vol 454 (1-3) ◽

pp. 30-35 ◽

Cited By ~ 4

Author(s):

Petar D. Todorov ◽

Carola Koper ◽

Joop H. van Lenthe ◽

Leonardus W. Jenneskens

Keyword(s):

Polycyclic Aromatic Hydrocarbons ◽

Gas Phase ◽

Aromatic Hydrocarbons ◽

Electron Affinities ◽

Polycyclic Aromatic

Download Full-text

Structure Resonance Theory. Correlations of Electron Affinities and Polarographic Reduction Potentials of Polycyclic Aromatic Hydrocarbons

Bulletin des Sociétés Chimiques Belges ◽

10.1002/bscb.19840931005 ◽

2010 ◽

Vol 93 (10) ◽

pp. 867-874 ◽

Cited By ~ 2

Author(s):

Admad S. Shawali ◽

Baghat E. Elanadouli ◽

Cyril Párkányi ◽

William C. Herndon

Keyword(s):

Polycyclic Aromatic Hydrocarbons ◽

Aromatic Hydrocarbons ◽

Polarographic Reduction ◽

Electron Affinities ◽

Resonance Theory ◽

Reduction Potentials ◽

Polycyclic Aromatic

Download Full-text

New schemes for the electron-capture sensitization of aromatic hydrocarbons

Journal of Chromatography A ◽

10.1016/s0021-9673(01)89014-2 ◽

1984 ◽

Vol 302 ◽

pp. 243-256 ◽

Cited By ~ 8

Author(s):

E.P. Grimsrud ◽

C.A. Valkenburg

Keyword(s):

Electron Capture ◽

Aromatic Hydrocarbons

Download Full-text

Electron Affinities and Ionization Potentials of Aromatic Hydrocarbons

Journal of the American Chemical Society ◽

10.1021/ja00898a004 ◽

1963 ◽

Vol 85 (15) ◽

pp. 2210-2214 ◽

Cited By ~ 60

Author(s):

Ralph S. Becker ◽

W. E. Wentworth

Keyword(s):

Aromatic Hydrocarbons ◽

Ionization Potentials ◽

Electron Affinities

Download Full-text

Chemistry of radical ions: the absolute rate constant of dimerization of radical anions of 1 ,1-diphenyl ethylene

Proceedings of the Royal Society of London Series A - Mathematical and Physical Sciences ◽

10.1098/rspa.1965.0214 ◽

1965 ◽

Vol 288 (1413) ◽

pp. 212-223 ◽

Cited By ~ 7

Keyword(s):

Electron Transfer ◽

Rate Constant ◽

Transfer Process ◽

Aromatic Hydrocarbons ◽

Radical Anions ◽

Electron Affinities ◽

Absolute Rate ◽

Radical Ions ◽

Electron Transfer Process ◽

Absolute Rate Constant

The combination of the labile radical ions, (Ph 2 C:CH 2 )7~, Na+, into dimeric dianions Na + , C - (Ph) 2 .CH 2 .CH 2 .C(Ph) - 2, Na+ was investigated by a flow and a stopflow technique. The bimolecular rate constant of combination was found to be 2 to 3 x 106 1. mole-1 s-1. The reaction was initiated by an electron transfer naphthalene^ + (P/*,2C:CH2) naphthalene+ (P/*,2C:CH^) or terphenylener + (P7fc2C:CH2) ⇔ terphenylene + (Pfe2C:CH^). The equilibrium constant of the first electron transfer process was found to be 20 and of the second about 16. These results are consistent with recent determinations of electron affinities of aromatic hydrocarbons.

Download Full-text