Electron capture by some molecules of biological significance and the determination of absolute electron affinities

1968 ◽  
Vol 21 (12) ◽  
pp. 2853 ◽  
Author(s):  
A Fulton ◽  
LE Lyons ◽  
GC Morris
Keyword(s):  
Electron Capture ◽  
Protoporphyrin Ix ◽  
Biological Significance ◽  
Molecular Orbitals ◽  
Electron Affinities ◽  
Metal Free ◽  
Capture Method

The electron capture method was applied to protoporphyrin IX and meso- porphyrin IX dimethyl esters, metal-free phthalocyanine, chlorophyll, riboflavine, nicotinamide, tetracene, and pentacene. The energy quantities obtained correlated with calculated energies of the lowest empty molecular orbitals of these molecules.

Electron affinities and the electron-capture method for aromatic hydrocarbons

1968 ◽  
Vol 72 (10) ◽  
pp. 3677-3678 ◽  
Author(s):  
Lawrence E. Lyons ◽  
G. C. Morris ◽  
L. J. Warren
Keyword(s):  
Electron Capture ◽  
Aromatic Hydrocarbons ◽  
Electron Affinities ◽  
Capture Method

Determination of multiple electron affinities of carbon disulfide using electron-capture detection

1998 ◽  
Vol 811 (1-2) ◽  
pp. 250-255 ◽  
Author(s):  
E.C.M Chen ◽  
Rajan George ◽  
Sandra Carr ◽  
W.E Wentworth ◽  
E.S.D Chen
Keyword(s):  
Electron Capture ◽  
Carbon Disulfide ◽  
Electron Capture Detection ◽  
Electron Affinities

Dissociation of imino proton(s) of a highly water-soluble metal-free phthalocyanine and determination of its pKa value in water

2013 ◽  
Vol 17 (06n07) ◽  
pp. 447-453 ◽  
Author(s):  
Hiroaki Isago ◽  
Harumi Fujita
Keyword(s):  
Aqueous Media ◽  
Thermal Reaction ◽  
Water Soluble ◽  
Acid Dissociation ◽  
Acid Dissociation Constant ◽  
Metal Free ◽  
Imino Proton ◽  
Pka Value ◽  
Triton X

Dissociation of imino proton(s) in the cavity of the macrocycle of a highly water-soluble, metal-free phthalocyanine ( H 2( H 4 tsppc ); where H 4 tsppc denotes tetrakis{(2′,6′-dimethyl-4′-sulfonic acid)phenoxy}phthalocyaninate) in ethanolic and aqueous solutions has spectrophotometrically been investigated. The spectral changes associated with reaction with NaOH have been found to involve one-proton transfer process in aqueous media while two-protons process in ethanolic media. The acid-dissociation constant of the first imino proton in water (in the presence of Triton X-100) has been determined to be 12.5 ± 0.2 (as pKa) at 25 °C. The doubly deprotonated species in EtOH has been easily converted to its corresponding cobalt(II) derivative by thermal reaction with anhydrous CoCl 2.

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