Kinetics and mechanism of the reversible nonenzymic deamination of aspartic acid

1970 ◽  
Vol 92 (9) ◽  
pp. 2774-2782 ◽  
Author(s):  
Jeffrey L. Bada ◽  
Stanley Lloyd. Miller
Keyword(s):  
Aspartic Acid ◽  
Kinetics And Mechanism

Kinetics and mechanism of the nonenzymatic reversible deamination of aspartic acid

1969 ◽  
Vol 91 (14) ◽  
pp. 3946-3948 ◽  
Author(s):  
Jeffrey L. Bada ◽  
Stanley Lloyd Miller
Keyword(s):  
Aspartic Acid ◽  
Kinetics And Mechanism

Kinetics and mechanism of the reversible isomerization of aspartic acid residues in tetrapeptides

1995 ◽  
pp. 437 ◽  
Author(s):  
Sante Capasso ◽  
Anthony J. Kirby ◽  
Severo Salvadori ◽  
Filomena Sica ◽  
Adriana Zagari
Keyword(s):  
Aspartic Acid ◽  
Kinetics And Mechanism

ChemInform Abstract: Kinetics and Mechanism of the Decarboxylation of Aspartic Acid with Ninhydrin.

ChemInform ◽  
2010 ◽  
Vol 23 (30) ◽  
pp. no-no
Author(s):  
Z. ZHAN ◽  
D. GUPTA ◽  
A. A. KHAN
Keyword(s):  
Aspartic Acid ◽  
Kinetics And Mechanism

Kinetics and Mechanism of Aspartic Acid Adsorption and Its Explosive Decomposition on Cu(100)

Langmuir ◽  
2019 ◽  
Vol 35 (8) ◽  
pp. 2925-2933 ◽  
Author(s):  
Burcu Karagoz ◽  
Aaron Reinicker ◽  
Andrew J. Gellman
Keyword(s):  
Aspartic Acid ◽  
Kinetics And Mechanism ◽  
Explosive Decomposition

scholarly journals Kinetics and Mechanism of Electron Transfer to Heptavalent Manganese byDL-Aspartic Acid in Alkaline Aqueous and Micellar Media

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
M. Sanjana ◽  
A. K. Patnaik ◽  
S. K. Badamali ◽  
P. Mohanty
Keyword(s):  
Electron Transfer ◽  
Spectral Analysis ◽  
Aspartic Acid ◽  
Sodium Dodecyl ◽  
Activation Parameters ◽  
Kinetics And Mechanism ◽  
Micellar Media ◽  
First Order ◽  
Order Dependence ◽  
Sphere Mechanism

The kinetics and mechanism of the electron transfer ofdl-Aspartic acid (Asp) by Mn (VII) in alkaline medium has been studied spectrophotometrically over the range2.0≤103[Asp]≤5.0 mol dm−3;0.01≤[OH-]≤0.05 mol dm−3;298≤T≤318 K andI=0.05 mol dm−3(KNO3). The reaction exhibits first-order dependence in[MnO4-]Tbut shows fractional-order dependence in both[Asp]Tand[OH−]T. The reaction was studied in the presence of sodium dodecyl sulfate (SDS); an increase in the rate with the increase in the micellar concentration was observed. The products were characterized by spectral analysis. A mechanism involving free radicals is proposed. Asp bindsMnO4-to form a complex that subsequently decomposes to products. Activation parametersΔH° (kJ mol−1) andΔS° (JK−1 mol−1) for the reaction are5.62±0.35and−227.65±1.1, respectively. The negative value ofΔS° indicates that oxidation occurs via inner sphere mechanism.

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