Metal ion probes of molecular geometry. II. Direct spectroscopic determination of the absolute configuration of hydroxyl bearing asymmetric centers based on the shift reagent, tris(1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionato)europium

1974 ◽  
Vol 96 (2) ◽  
pp. 603-604 ◽  
Author(s):  
Niels H. Andersen ◽  
B. J. Bottino ◽  
Ana Moore ◽  
James R. Shaw
Keyword(s):  
Absolute Configuration ◽  
Metal Ion ◽  
Molecular Geometry ◽  
Shift Reagent ◽  
Spectroscopic Determination ◽  
The Absolute

Determination of the absolute configuration of natural products

2014 ◽  
Vol 11 (3) ◽  
pp. 193-198 ◽  
Author(s):  
Ling-Yi KONG ◽  
Peng WANG
Keyword(s):  
Natural Products ◽  
Absolute Configuration ◽  
The Absolute

scholarly journals Rapid Organocatalytic Chirality Analysis of Amines, Amino Acids, Alcohols, Amino Alcohols and Diols with Achiral Iso(thio)cyanate Probes

2021 ◽  
Author(s):  
Eryn Nelson ◽  
Jeffrey S. S. K. Formen ◽  
Christian Wolf
Keyword(s):  
Amino Acids ◽  
Absolute Configuration ◽  
Rapid Determination ◽  
Amino Alcohols ◽  
Enantioselective Synthesis ◽  
Widespread Occurrence ◽  
Chiral Compounds ◽  
New Methods ◽  
The Absolute

The widespread occurrence and significance of chiral compounds does not only require new methods for their enantioselective synthesis but also efficient tools that allow rapid determination of the absolute configuration,...

scholarly journals Preparative-scale HPLC Resolution of Metallacyclic η3-Allyltricarbonyliron Complexes and Determination of the Absolute Configuration by X-Ray Crystal Structure Analysis

1999 ◽  
Vol 23 (9) ◽  
pp. 578-579
Author(s):  
Rainer Schobert ◽  
Hermann Pfab ◽  
Jutta Böhmer ◽  
Frank Hampel ◽  
Andreas Werner
Keyword(s):  
Crystal Structure ◽  
Silica Gel ◽  
Structure Analysis ◽  
Absolute Configuration ◽  
Crystal Structure Analysis ◽  
Preparative Scale ◽  
X Ray ◽  
The Absolute

Racemates of (η3-allyl)tricarbonyliron lactone complex Fe(CO)3{η1:η3-C(O)XCH2CHCMeCH2} 1a (X = O) and (η3-allyl)tricarbonyliron lactam complex 2a (X = NMe) are resolved on a preparative scale by HPLC on cellulose tris(3,5-dimethylphenyl)carbamate/silica gel RP-8 and the absolute configuration of (-)-2a is determined by X-ray crystal structure analysis.

Asymmetric Total Synthesis and Determination of the Absolute Configuration of (+)-Srilankenyne via Sequence-Sensitive Halogenations Guided by Conformational Analysis

2021 ◽  
Vol 23 (4) ◽  
pp. 1321-1326
Author(s):  
Hongjun Jang ◽  
Soo Yeon Kwak ◽  
Dongjoo Lee ◽  
Juan V. Alegre-Requena ◽  
Hyoungsu Kim ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Conformational Analysis ◽  
Absolute Configuration ◽  
Asymmetric Total Synthesis ◽  
The Absolute

ChemInform Abstract: Determination of the Absolute Configuration of Marine Oxylipin Topsentolide A1 by the Synthesis of the Enantiomer of the Natural Product.

ChemInform ◽  
2010 ◽  
Vol 41 (34) ◽  
pp. no-no
Author(s):  
Munetaka Kobayashi ◽  
Ken Ishigami ◽  
Hidenori Watanabe
Keyword(s):  
Natural Product ◽  
Absolute Configuration ◽  
The Absolute

Determination of the Absolute Configuration of Two Pairs of C-8 − C-9′ Linked Neolignan Enantiomers

Chirality ◽  
2014 ◽  
Vol 26 (12) ◽  
pp. 825-828
Author(s):  
Jing-Mei Bao ◽  
Zhong-Bin Cheng ◽  
Jun-Sheng Zhang ◽  
Jian-Yong Zhu ◽  
Gui-Hua Tang ◽  
...  
Keyword(s):  
Absolute Configuration ◽  
The Absolute
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