Crystal and Molecular Structure of Metal Ion-Aromatic Complexes. I. The Cuprous Ion-Benzene Complex, C6H6·CuAlCl4

1963 ◽  
Vol 85 (24) ◽  
pp. 4046-4047 ◽  
Author(s):  
R. W. Turner ◽  
E. L. Amma
Keyword(s):  
Molecular Structure ◽  
Metal Ion ◽  
Crystal And Molecular Structure ◽  
Structure Of Metal ◽  
Aromatic Complexes ◽  
Cuprous Ion

Metal ion-aromatic complexes. VII. Crystal and molecular structure of bis(m-xylene)silver perchlorate

1969 ◽  
Vol 91 (21) ◽  
pp. 5745-5749 ◽  
Author(s):  
I. F. Taylor ◽  
E. A. Hall ◽  
E. L. Amma
Keyword(s):  
Molecular Structure ◽  
Metal Ion ◽  
Crystal And Molecular Structure ◽  
Silver Perchlorate ◽  
Aromatic Complexes

Metal Ion-Aromatic Complexes. III. The Crystal and Molecular Structure of C6H6·CuAlCl4

1966 ◽  
Vol 88 (9) ◽  
pp. 1877-1882 ◽  
Author(s):  
R. W. Turner ◽  
E. L. Amma
Keyword(s):  
Molecular Structure ◽  
Metal Ion ◽  
Crystal And Molecular Structure ◽  
Aromatic Complexes

Synthesis, IR and X-Ray Studies of Tetra(N,N′-tetraethyl-N″-benzoyl- phosphorictriamide)-tetra(μ-3-methoxo)-tetra(methanol)tetra-NickeI(II)

1998 ◽  
Vol 53 (8) ◽  
pp. 836-840 ◽  
Author(s):  
Vladimir A. Ovchynnikov ◽  
Vladimir M. Amirkhanov ◽  
Anatoliy A. Kapshuk ◽  
Tatyana Yu. Sliva ◽  
Tadeusz Glowiak ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Oxygen Atom ◽  
Metal Ion ◽  
Crystal And Molecular Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Octahedral Environment ◽  
Distorted Octahedral ◽  
Methoxy Groups ◽  
Oxygen Atoms

Abstract A new nickel(II) complex with N,N′-tetraethyl-N″-benzoylphosphortriamide (HL = C6H5C(O)N(H)P(O)(NEt2)2) of composition Ni4L4(OCH3)4·(HOCH3)4 (1) has been synthe­ sized. The crystal and molecular structure of 1 has been determined from the X-Ray diffraction data (tetragonal, space group P4̄21c with a = 17.000(2) Å, c = 15.338(3) Å, Z = 2; R = 0.0399 for 1412 unique reflections). The structure is made up of cubane-like tetramers. In the corners of a cube there are 4 atoms of nickel and 4 atoms of oxygen of methoxy groups. The nickel atoms are characterized by a slightly distorted octahedral environment, which consists of three oxygen atoms of methoxy groups, carbonylic and phosphorylic oxygen atoms of the ligand L-, and an oxygen atom of a methanol molecule. The ligands L- coordinate to the metal ion forming a chelate via the oxygen atoms of carbonylic and phosphorylic groups.

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