Molecular Orbital Theory and the Near Ultraviolet Absorption Spectrum of Monosubstituted Benzenes. IV. The Phenyl Halides and the Inductive Effect

1950 ◽  
Vol 72 (11) ◽  
pp. 5252-5256 ◽  
Author(s):  
W. W. Robertson ◽  
F. A. Matsen
Keyword(s):  
Absorption Spectrum ◽  
Molecular Orbital ◽  
Inductive Effect ◽  
Ultraviolet Absorption ◽  
Ultraviolet Absorption Spectrum ◽  
Molecular Orbital Theory ◽  
Orbital Theory ◽  
Near Ultraviolet ◽  
Monosubstituted Benzenes

ChemInform Abstract: THE NEAR-ULTRAVIOLET ABSORPTION SPECTRUM OF DIIMIDE- A RE-EXAMINATION

1978 ◽  
Vol 9 (38) ◽  
Author(s):  
R. A. BACK ◽  
C. WILLIS ◽  
D. A. RAMSAY
Keyword(s):  
Absorption Spectrum ◽  
Ultraviolet Absorption ◽  
Ultraviolet Absorption Spectrum ◽  
Near Ultraviolet

The Near Ultraviolet Absorption Spectrum of Monodeuterobenzene

1942 ◽  
Vol 10 (9) ◽  
pp. 575-581 ◽  
Author(s):  
C. A. Beck ◽  
H. Sponer
Keyword(s):  
Absorption Spectrum ◽  
Ultraviolet Absorption ◽  
Ultraviolet Absorption Spectrum ◽  
Near Ultraviolet

The Near-ultraviolet Absorption Spectrum of Diimide in Liquid Ammonia and its Decomposition between −65 and −38 °C

1974 ◽  
Vol 52 (13) ◽  
pp. 2513-2515 ◽  
Author(s):  
R. A. Back ◽  
C. Willis
Keyword(s):  
Absorption Spectrum ◽  
Gas Phase ◽  
Room Temperature ◽  
Liquid Ammonia ◽  
Vibrational Structure ◽  
Ultraviolet Absorption ◽  
Ultraviolet Absorption Spectrum ◽  
First Order ◽  
Rapid Decomposition ◽  
Near Ultraviolet

The near-ultraviolet absorption spectrum of diimide in liquid ammonia at −50 °C is shifted about 500 Å to the red compared with the gas-phase spectrum, with λmax = 4000 Å. The spectrum is also broadened and the vibrational structure largely obscured. It is suggested that hydrogen bonding is responsible for these changes.Diimide is much more stable in liquid ammonia between −65 and −38 °C than in the gas phase at room temperature. A first-order decay is observed with Arrhenius parameters of A = 1.9 × 103 s−1 and E = 6.6 kcal/mol; this is always preceded by a more rapid, higher-order initial decay which may be related to the rapid decomposition observed during vaporization.

Near-Ultraviolet Absorption Spectrum of 5,10-Dihydrophenazine

1968 ◽  
Vol 22 (6) ◽  
pp. 785-786 ◽  
Author(s):  
David N. Bailey ◽  
David K. Roe ◽  
David M. Hercules
Keyword(s):  
Absorption Spectrum ◽  
Ultraviolet Absorption ◽  
Ultraviolet Absorption Spectrum ◽  
Near Ultraviolet

Near‐Ultraviolet Absorption Spectrum of Benzaldehyde Vapor

1951 ◽  
Vol 19 (3) ◽  
pp. 389-389 ◽  
Author(s):  
Sunao Imanishi
Keyword(s):  
Absorption Spectrum ◽  
Ultraviolet Absorption ◽  
Ultraviolet Absorption Spectrum ◽  
Near Ultraviolet

Analysis of the Near Ultraviolet Absorption Spectrum of 1,2,4,5‐Tetrachlorobenzene Vapor

1956 ◽  
Vol 24 (3) ◽  
pp. 595-601 ◽  
Author(s):  
Ikuo Matubara ◽  
Tosinobu Anno
Keyword(s):  
Absorption Spectrum ◽  
Ultraviolet Absorption ◽  
Ultraviolet Absorption Spectrum ◽  
Near Ultraviolet

Near Ultraviolet Absorption Spectrum of Tropolone Vapor

1956 ◽  
Vol 24 (6) ◽  
pp. 1272-1272 ◽  
Author(s):  
Sunao Imanishi ◽  
Mitsuo Ito
Keyword(s):  
Absorption Spectrum ◽  
Ultraviolet Absorption ◽  
Ultraviolet Absorption Spectrum ◽  
Near Ultraviolet
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