Total Synthesis of (+)-Aspidospermidine:  A New Strategy for the Enantiospecific Synthesis of Aspidosperma Alkaloids

2002 ◽  
Vol 124 (45) ◽  
pp. 13398-13399 ◽  
Author(s):  
Joseph P. Marino ◽  
Maria B. Rubio ◽  
Ganfeng Cao ◽  
Alfonso de Dios

1983 ◽  
Vol 48 (13) ◽  
pp. 2298-2300 ◽  
Author(s):  
Luciano Lombardo ◽  
Lewis N. Mander




2015 ◽  
Vol 10 (1) ◽  
pp. 1934578X1501000
Author(s):  
Carmen Pérez Morales ◽  
M. Mar Herrador ◽  
José F. Quílez del Moral ◽  
Alejandro F. Barrero

Following the principles of collective total synthesis, a number of natural products sharing an optically pure, multifunctional, cyclopentanic core were synthesized from a common precursor: plinol A (1). This intermediate was efficiently obtained in only four steps from (-)-linalool (2) using as the key step a Ti(III)-mediated diastereoselective radical cyclization. The feasibility of this approach was confirmed with the expedient enantiospecific synthesis of cyclonerodiol (3), and the formal synthesis of chocol G (4) and piperitone (5).





2018 ◽  
Vol 37 (9) ◽  
pp. 461-470
Author(s):  
Yunpeng Zou ◽  
Tao Peng ◽  
Gang Wang ◽  
Xiaoxue Wen ◽  
Shuchen Liu ◽  
...  


ChemInform ◽  
2010 ◽  
Vol 30 (25) ◽  
pp. no-no
Author(s):  
P. John Biju ◽  
G. S. R. Subba Rao
Keyword(s):  


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