Highly Electrophilic Olefin Polymerization Catalysts. Counteranion and Solvent Effects on Constrained Geometry Catalyst Ion Pair Structure and Reactivity

Journal of the American Chemical Society ◽

10.1021/ja980852n ◽

1998 ◽

Vol 120 (32) ◽

pp. 8257-8258 ◽

Author(s):

Giuseppe Lanza ◽

Ignazio L. Fragalà ◽

Tobin J. Marks

Keyword(s):

Solvent Effects ◽

Olefin Polymerization ◽

Ion Pair ◽

Polymerization Catalysts ◽

Constrained Geometry ◽

Constrained Geometry Catalyst

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Highly Electrophilic Olefin Polymerization Catalysts. Quantitative Reaction Coordinates for Fluoroarylborane/Alumoxane Methide Abstraction and Ion-Pair Reorganization in Group 4 Metallocene and “Constrained Geometry” Catalysts

Journal of the American Chemical Society ◽

10.1021/ja972912f ◽

1998 ◽

Vol 120 (8) ◽

pp. 1772-1784 ◽

Author(s):

Paul A. Deck ◽

Colin L. Beswick ◽

Tobin J. Marks

Keyword(s):

Olefin Polymerization ◽

Ion Pair ◽

Polymerization Catalysts ◽

Reaction Coordinates ◽

Group 4 ◽

Constrained Geometry

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Highly Electrophilic Olefin Polymerization Catalysts. Quantitative Reaction Coordinates for Fluoroarylborane/Alumoxane Methide Abstraction and Ion−Pair Reorganization in Group 4 Metallocene and “Constrained Geometry” CatalystsJ. Am. Chem. Soc.1998,120, 1772−1784

Journal of the American Chemical Society ◽

10.1021/ja9855242 ◽

1998 ◽

Vol 120 (46) ◽

pp. 12167-12167 ◽

Author(s):

Paul A. Deck ◽

Colin L. Beswick ◽

Tobin J. Marks

Keyword(s):

Olefin Polymerization ◽

Ion Pair ◽

Polymerization Catalysts ◽

Reaction Coordinates ◽

Group 4 ◽

Constrained Geometry

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Density Functional Study on Activation and Ion-Pair Formation in Group IV Metallocene and Related Olefin Polymerization Catalysts

Organometallics ◽

10.1021/om9903285 ◽

1999 ◽

Vol 18 (22) ◽

pp. 4624-4636 ◽

Author(s):

Mary S. W. Chan ◽

Kumar Vanka ◽

Cory C. Pye ◽

Tom Ziegler

Keyword(s):

Density Functional ◽

Olefin Polymerization ◽

Ion Pair ◽

Pair Formation ◽

Group Iv ◽

Functional Study ◽

Polymerization Catalysts ◽

Density Functional Study ◽

Ion Pair Formation

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DFT theoretical studies of UV–Vis spectra and solvent effects in olefin polymerization catalysts

Chemical Physics Letters ◽

10.1016/j.cplett.2004.11.089 ◽

2005 ◽

Vol 401 (4-6) ◽

pp. 515-521 ◽

Author(s):

P.G. Belelli ◽

D.E. Damiani ◽

N.J. Castellani

Keyword(s):

Solvent Effects ◽

Olefin Polymerization ◽

Theoretical Studies ◽

Polymerization Catalysts

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Cationic Metallocene Olefin Polymerization Catalysts. Thermodynamic and Kinetic Parameters for Ion Pair Formation, Dissociation, and Reorganization

Journal of the American Chemical Society ◽

10.1021/ja00127a029 ◽

1995 ◽

Vol 117 (22) ◽

pp. 6128-6129 ◽

Author(s):

Paul A. Deck ◽

Tobin J. Marks

Keyword(s):

Kinetic Parameters ◽

Olefin Polymerization ◽

Ion Pair ◽

Pair Formation ◽

Polymerization Catalysts ◽

Ion Pair Formation ◽

Thermodynamic And Kinetic Parameters

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A Novel Phenolate “Constrained Geometry” Catalyst System. Efficient Synthesis, Structural Characterization, and α-Olefin Polymerization Catalysis

Organometallics ◽

10.1021/om9707376 ◽

1997 ◽

Vol 16 (26) ◽

pp. 5958-5963 ◽

Author(s):

You-Xian Chen ◽

Peng-Fei Fu ◽

Charlotte L. Stern ◽

Tobin J. Marks

Keyword(s):

Structural Characterization ◽

Olefin Polymerization ◽

Catalyst System ◽

Efficient Synthesis ◽

Constrained Geometry ◽

Polymerization Catalysis ◽

Constrained Geometry Catalyst

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A Sterically Expanded “Constrained Geometry Catalyst” for Highly Active Olefin Polymerization and Copolymerization: An Unyielding Comonomer Effect

Journal of the American Chemical Society ◽

10.1021/ja044678g ◽

2004 ◽

Vol 126 (51) ◽

pp. 16716-16717 ◽

Author(s):

Levi J. Irwin ◽

Joseph H. Reibenspies ◽

Stephen A. Miller

Keyword(s):

Olefin Polymerization ◽

Highly Active ◽

Constrained Geometry ◽

Constrained Geometry Catalyst

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Ligand Substituent, Anion, and Solvation Effects on Ion Pair Structure, Thermodynamic Stability, and Structural Mobility in “Constrained Geometry” Olefin Polymerization Catalysts: an Ab Initio Quantum Chemical Investigation

Journal of the American Chemical Society ◽

10.1021/ja000571r ◽

2000 ◽

Vol 122 (51) ◽

pp. 12764-12777 ◽

Author(s):

Giuseppe Lanza ◽

Ignazio L. Fragalà ◽

Tobin J. Marks

Keyword(s):

Ab Initio ◽

Thermodynamic Stability ◽

Quantum Chemical ◽

Ion Pair ◽

Chemical Investigation ◽

Polymerization Catalysts ◽

Quantum Chemical Investigation ◽

Solvation Effects ◽

Constrained Geometry ◽

Structural Mobility

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Catalytic Olefin Polymerization, Proceedings of the International Symposium on Recent Developments in Olefin Polymerization Catalysts

10.1016/s0167-2991(08)x6041-0 ◽

1990 ◽

Keyword(s):

International Symposium ◽

Olefin Polymerization ◽

Polymerization Catalysts ◽

Recent Developments

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Highly Efficient Carborane-Based Activators for Molecular Olefin Polymerization Catalysts

ACS Catalysis ◽

10.1021/acscatal.0c04228 ◽

2021 ◽

pp. 3335-3342

Author(s):

S. Olivia Gunther ◽

Qingheng Lai ◽

Todd Senecal ◽

Rafael Huacuja ◽

Sean Bremer ◽

...

Keyword(s):

Olefin Polymerization ◽

Polymerization Catalysts ◽

Highly Efficient

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