Highly Electrophilic Olefin Polymerization Catalysts. Quantitative Reaction Coordinates for Fluoroarylborane/Alumoxane Methide Abstraction and Ion−Pair Reorganization in Group 4 Metallocene and “Constrained Geometry” CatalystsJ. Am. Chem. Soc.1998,120, 1772−1784

Paul A. Deck; Colin L. Beswick; Tobin J. Marks

doi:10.1021/ja9855242

Highly Electrophilic Olefin Polymerization Catalysts. Quantitative Reaction Coordinates for Fluoroarylborane/Alumoxane Methide Abstraction and Ion−Pair Reorganization in Group 4 Metallocene and “Constrained Geometry” CatalystsJ. Am. Chem. Soc.1998,120, 1772−1784

Journal of the American Chemical Society ◽

10.1021/ja9855242 ◽

1998 ◽

Vol 120 (46) ◽

pp. 12167-12167 ◽

Cited By ~ 3

Author(s):

Paul A. Deck ◽

Colin L. Beswick ◽

Tobin J. Marks

Keyword(s):

Olefin Polymerization ◽

Ion Pair ◽

Polymerization Catalysts ◽

Reaction Coordinates ◽

Group 4 ◽

Constrained Geometry

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Highly Electrophilic Olefin Polymerization Catalysts. Quantitative Reaction Coordinates for Fluoroarylborane/Alumoxane Methide Abstraction and Ion-Pair Reorganization in Group 4 Metallocene and “Constrained Geometry” Catalysts

Journal of the American Chemical Society ◽

10.1021/ja972912f ◽

1998 ◽

Vol 120 (8) ◽

pp. 1772-1784 ◽

Cited By ~ 89

Author(s):

Paul A. Deck ◽

Colin L. Beswick ◽

Tobin J. Marks

Keyword(s):

Olefin Polymerization ◽

Ion Pair ◽

Polymerization Catalysts ◽

Reaction Coordinates ◽

Group 4 ◽

Constrained Geometry

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Highly Electrophilic Olefin Polymerization Catalysts. Counteranion and Solvent Effects on Constrained Geometry Catalyst Ion Pair Structure and Reactivity

Journal of the American Chemical Society ◽

10.1021/ja980852n ◽

1998 ◽

Vol 120 (32) ◽

pp. 8257-8258 ◽

Cited By ~ 45

Author(s):

Giuseppe Lanza ◽

Ignazio L. Fragalà ◽

Tobin J. Marks

Keyword(s):

Solvent Effects ◽

Olefin Polymerization ◽

Ion Pair ◽

Polymerization Catalysts ◽

Constrained Geometry ◽

Constrained Geometry Catalyst

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Density Functional Study on Activation and Ion-Pair Formation in Group IV Metallocene and Related Olefin Polymerization Catalysts

Organometallics ◽

10.1021/om9903285 ◽

1999 ◽

Vol 18 (22) ◽

pp. 4624-4636 ◽

Cited By ~ 63

Author(s):

Mary S. W. Chan ◽

Kumar Vanka ◽

Cory C. Pye ◽

Tom Ziegler

Keyword(s):

Density Functional ◽

Olefin Polymerization ◽

Ion Pair ◽

Pair Formation ◽

Group Iv ◽

Functional Study ◽

Polymerization Catalysts ◽

Density Functional Study ◽

Ion Pair Formation

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Group 4 Metal Olefin Polymerization Catalysts Stabilized by Bidentate O,P Ligands

Organometallics ◽

10.1021/om7008149 ◽

2008 ◽

Vol 27 (2) ◽

pp. 235-245 ◽

Cited By ~ 56

Author(s):

Richard J. Long ◽

Vernon C. Gibson ◽

Andrew J. P. White

Keyword(s):

Olefin Polymerization ◽

Polymerization Catalysts ◽

Group 4 ◽

Group 4 Metal ◽

P Ligands

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Synthesis, Structure, and Olefin Polymerization Behavior of Constrained-Geometry Group 4 Metallacarboranes Incorporating Imido-Dicarbollyl Ligands

Organometallics ◽

10.1021/om060125y ◽

2006 ◽

Vol 25 (10) ◽

pp. 2578-2584 ◽

Cited By ~ 32

Author(s):

Mingli Gao ◽

Yong Tang ◽

Meihua Xie ◽

Changtao Qian ◽

Zuowei Xie

Keyword(s):

Olefin Polymerization ◽

Group 4 ◽

Constrained Geometry ◽

Polymerization Behavior

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Group 4 complexes bearing tridentate aryloxide-based ancillary ligands : synthesis, characterization and application as olefin polymerization catalysts

10.5353/th_b3672722 ◽

2006 ◽

Author(s):

Ka-ho Tam

Keyword(s):

Olefin Polymerization ◽

Polymerization Catalysts ◽

Ancillary Ligands ◽

Group 4

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Group 4 metallocene-alumoxane olefin polymerization catalysts. CPMAS-NMR spectroscopic observation of cation-like zirconocene alkyls

Journal of the American Chemical Society ◽

10.1021/ja00029a063 ◽

1992 ◽

Vol 114 (3) ◽

pp. 1112-1114 ◽

Cited By ~ 133

Author(s):

Chand Sishta ◽

Robin M. Hathorn ◽

Tobin J. Marks

Keyword(s):

Olefin Polymerization ◽

Spectroscopic Observation ◽

Polymerization Catalysts ◽

Group 4

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One-Component Group 4 Homogeneous Ziegler-Natta Olefin Polymerization Catalysts: Hydroboration of Zirconium Bisalkyls with Pendant 2-Propenyl Groups Using [(C6F5)2BH]2

Organometallics ◽

10.1021/om00010a028 ◽

1995 ◽

Vol 14 (10) ◽

pp. 4617-4624 ◽

Cited By ~ 47

Author(s):

Rupert E. v. H. Spence ◽

Warren E. Piers

Keyword(s):

Olefin Polymerization ◽

Polymerization Catalysts ◽

Component Group ◽

Group 4

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Cationic Metallocene Olefin Polymerization Catalysts. Thermodynamic and Kinetic Parameters for Ion Pair Formation, Dissociation, and Reorganization

Journal of the American Chemical Society ◽

10.1021/ja00127a029 ◽

1995 ◽

Vol 117 (22) ◽

pp. 6128-6129 ◽

Cited By ~ 53

Author(s):

Paul A. Deck ◽

Tobin J. Marks

Keyword(s):

Kinetic Parameters ◽

Olefin Polymerization ◽

Ion Pair ◽

Pair Formation ◽

Polymerization Catalysts ◽

Ion Pair Formation ◽

Thermodynamic And Kinetic Parameters

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“Double Activation” of Constrained Geometry andansa-Metallocene Group 4 Metal Dialkyls: Synthesis, Structure, and Olefin Polymerization Study of Mono- and Dicationic Aluminate Complexes

Journal of the American Chemical Society ◽

10.1021/ja002654d ◽

2001 ◽

Vol 123 (4) ◽

pp. 745-746 ◽

Cited By ~ 52

Author(s):

Eugene Y.-X. Chen ◽

William J. Kruper ◽

Gordon Roof ◽

David R. Wilson

Keyword(s):

Olefin Polymerization ◽

Group 4 ◽

Constrained Geometry ◽

Double Activation ◽

Group 4 Metal

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