Kinetically Controlled Stepwise Self-Assembly of AuI-Metallopeptides in Water

2018 ◽  
Vol 140 (2) ◽  
pp. 534-537 ◽  
Author(s):  
Benedict Kemper ◽  
Lydia Zengerling ◽  
Daniel Spitzer ◽  
Ronja Otter ◽  
Tobias Bauer ◽  
...  

2009 ◽  
Vol 131 (7) ◽  
pp. 2422-2423 ◽  
Author(s):  
Daniel Lubrich ◽  
Simon J. Green ◽  
Andrew J. Turberfield


2007 ◽  
Vol 111 (3) ◽  
pp. 1347-1354 ◽  
Author(s):  
Todd C. Schwendemann ◽  
Indraneel Samanta ◽  
Tobias Kunstmann ◽  
Ian Harrison


Nanoscale ◽  
2019 ◽  
Vol 11 (13) ◽  
pp. 5891-5895
Author(s):  
Tao Zhou ◽  
Jijo J. Vallooran ◽  
Raffaele Mezzenga

Kinetically controlled supramolecular chirality was achieved by biocatalytic self-assembly in Lipidic cubic mesophases (LCMs). During aging, thermodynamically stable organic crystals are formed.



CCS Chemistry ◽  
2019 ◽  
Vol 1 (2) ◽  
pp. 173-180 ◽  
Author(s):  
Luyang Zhao ◽  
Shukun Li ◽  
Yamei Liu ◽  
Ruirui Xing ◽  
Xuehai Yan

Supramolecular assembly could in principle lead to redshifted absorption through J-aggregation of chromophores, which would be a highly promising method for achieving near-infrared materials with improved functionality and flexibility. To effectively enhance the material functionalities, one of the great challenges remaining is to achieve an aggregation state with a redshift larger than 100 nm. Conventional assemblies that are mostly thermodynamically controlled have a limited redshifted absorption of less than 30 nm. In this work, using a model phthalocyanine–peptide conjugate compound, we achieved the first fabrication of phthalocyanine-based near-infrared materials with a superlarge absorption redshift of 105 nm by a kinetically controlled self-assembly strategy. In this kinetically controlled self-assembly process, sufficient rearrangement of intermolecular aggregates to an ordered structure is revealed to be crucial to facilitate the formation of nanofibrils instead of nanoparticles, which are formed via a general rapid self-assembly pathway under thermodynamic control. The superlarge redshift in the absorbance of assembled nanofibrils originates from the orderly stacked phthalocyanine chromophores, which enable a charge transfer state through more effective intermolecular orbital overlapping. The kinetically controlled J-aggregation state of the phthalocyanine–peptide conjugate with superlarge redshifted absorption not only opens an unprecedented route toward novel near-infrared phthalocyanine materials but also holds great promise for revealing general design principles for various organic dye materials.



Langmuir ◽  
2018 ◽  
Vol 35 (1) ◽  
pp. 141-149 ◽  
Author(s):  
Zhengping Tan ◽  
Wei Lan ◽  
Qianqian Liu ◽  
Ke Wang ◽  
Mubashir Hussain ◽  
...  


2013 ◽  
Vol 19 (6) ◽  
pp. 1882-1885 ◽  
Author(s):  
Ming Hu ◽  
Shinsuke Ishihara ◽  
Katsuhiko Ariga ◽  
Masataka Imura ◽  
Yusuke Yamauchi


Author(s):  
Zizhao Huang ◽  
Tao Jiang ◽  
Jie Wang ◽  
Xiang Ma ◽  
He Tian


2006 ◽  
Vol 8 (10) ◽  
pp. 2159-2162 ◽  
Author(s):  
Brian H. Northrop ◽  
Saeed J. Khan ◽  
J. Fraser Stoddart


2018 ◽  
Vol 51 (2) ◽  
pp. 465-474 ◽  
Author(s):  
Ryan D. Brown ◽  
Steven A. Corcelli ◽  
S. Alex Kandel


2017 ◽  
Vol 17 (4) ◽  
pp. 1707-1715 ◽  
Author(s):  
Minwook Park ◽  
Won-Jin Yoon ◽  
Dae-Yoon Kim ◽  
Yu-Jin Choi ◽  
Jahyeon Koo ◽  
...  


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