Kinetic Isotope Effects Provide Experimental Evidence for Proton Tunneling in Methylammonium Lead Triiodide Perovskites

2017 ◽  
Vol 139 (45) ◽  
pp. 16359-16364 ◽  
Author(s):  
Yan-Fang Chen ◽  
Yu-Tang Tsai ◽  
Lionel Hirsch ◽  
Dario M. Bassani
Keyword(s):  
Experimental Evidence ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Proton Tunneling ◽  
Kinetic Isotope

scholarly journals Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular12C/13C Kinetic Isotope Effects

2010 ◽  
Vol 132 (36) ◽  
pp. 12548-12549 ◽  
Author(s):  
Ollie M. Gonzalez-James ◽  
Xue Zhang ◽  
Ayan Datta ◽  
David A. Hrovat ◽  
Weston Thatcher Borden ◽  
...  
Keyword(s):  
Experimental Evidence ◽  
Ring Opening ◽  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope

Intramolecular and Intermolecular Kinetic Isotope Effects (KIE) in the Nitrosoarene Ene Reaction:  Experimental Evidence for Reversible Intermediate Formation

2003 ◽  
Vol 68 (6) ◽  
pp. 2420-2425 ◽  
Author(s):  
Waldemar Adam ◽  
Oliver Krebs ◽  
Michael Orfanopoulos ◽  
Manolis Stratakis ◽  
Georgios C. Vougioukalakis
Keyword(s):  
Experimental Evidence ◽  
Isotope Effects ◽  
Intermediate Formation ◽  
Kinetic Isotope Effects ◽  
Ene Reaction ◽  
Kinetic Isotope

Primary and secondary kinetic isotope effects in proton (H+/D+) and chloronium ion (35Cl+/37Cl+) affinities

2001 ◽  
Vol 36 (10) ◽  
pp. 1140-1148 ◽  
Author(s):  
F�bio Cesar Gozzo ◽  
Marcos N. Eberlin
Keyword(s):  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope

Theoretical Simulations of Heavy-Atom Kinetic Isotope Effects in Aliphatic Claisen Rearrangement

2020 ◽  
Vol 124 (51) ◽  
pp. 10678-10686
Author(s):  
Yuqing Xu ◽  
Kin-Yiu Wong ◽  
Meishan Wang ◽  
Desheng Liu ◽  
Wenkai Zhao ◽  
...  
Keyword(s):  
Claisen Rearrangement ◽  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
Theoretical Simulations

Direct dynamics calculations of reaction rate and kinetic isotope effects in enzyme catalysed reactions

2002 ◽  
Vol 122 ◽  
pp. 223-242 ◽  
Author(s):  
Gary Tresadern ◽  
Sara Nunez ◽  
Paul F. Faulder ◽  
Hong Wang ◽  
Ian H. Hillier ◽  
...  
Keyword(s):  
Reaction Rate ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Direct Dynamics ◽  
Kinetic Isotope

Interpretation of Transient-State Kinetic Isotope Effects†

Biochemistry ◽  
1996 ◽  
Vol 35 (1) ◽  
pp. 83-88 ◽  
Author(s):  
Harvey F. Fisher ◽  
Swapan K. Saha
Keyword(s):  
Isotope Effects ◽  
Transient State ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
State Kinetic
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