Intramolecular and Intermolecular Kinetic Isotope Effects (KIE) in the Nitrosoarene Ene Reaction:  Experimental Evidence for Reversible Intermediate Formation

Waldemar Adam; Oliver Krebs; Michael Orfanopoulos; Manolis Stratakis; Georgios C. Vougioukalakis

doi:10.1021/jo0266240

Intramolecular and Intermolecular Kinetic Isotope Effects (KIE) in the Nitrosoarene Ene Reaction: Experimental Evidence for Reversible Intermediate Formation

The Journal of Organic Chemistry ◽

10.1021/jo0266240 ◽

2003 ◽

Vol 68 (6) ◽

pp. 2420-2425 ◽

Cited By ~ 17

Author(s):

Waldemar Adam ◽

Oliver Krebs ◽

Michael Orfanopoulos ◽

Manolis Stratakis ◽

Georgios C. Vougioukalakis

Keyword(s):

Experimental Evidence ◽

Isotope Effects ◽

Intermediate Formation ◽

Kinetic Isotope Effects ◽

Ene Reaction ◽

Kinetic Isotope

ChemInform Abstract: Ene Reaction Mechanisms. Part 3. Intermolecular and Intramolecular Kinetic Isotope Effects (KIE) for Some Ene Reactions of Hetero Enophiles.

Chemischer Informationsdienst ◽

10.1002/chin.198625093 ◽

1986 ◽

Vol 17 (25) ◽

Author(s):

W. STARFLINGER ◽

G. KRESZE ◽

K. HUSS

Keyword(s):

Reaction Mechanisms ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Ene Reactions ◽

Ene Reaction ◽

Kinetic Isotope

Mechanism of the dimethyl mesoxalate-alkene ene reaction. Deuterium kinetic isotope effects

The Journal of Organic Chemistry ◽

10.1021/jo01311a046 ◽

1980 ◽

Vol 45 (23) ◽

pp. 4774-4776 ◽

Cited By ~ 14

Author(s):

Osman Achmatowicz ◽

Jan Szymoniak

Keyword(s):

Isotope Effects ◽

Kinetic Isotope Effects ◽

Ene Reaction ◽

Kinetic Isotope

Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular12C/13C Kinetic Isotope Effects

Journal of the American Chemical Society ◽

10.1021/ja1055593 ◽

2010 ◽

Vol 132 (36) ◽

pp. 12548-12549 ◽

Cited By ~ 66

Author(s):

Ollie M. Gonzalez-James ◽

Xue Zhang ◽

Ayan Datta ◽

David A. Hrovat ◽

Weston Thatcher Borden ◽

...

Keyword(s):

Experimental Evidence ◽

Ring Opening ◽

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Kinetic Isotope

Kinetic isotope effects and intermediate formation for the aqueous alkaline homogeneous hydrolysis of 1,3,5-triaza-1,3,5-trinitrocyclohexane (RDX)

The Journal of Physical Chemistry ◽

10.1021/j100520a003 ◽

1977 ◽

Vol 81 (5) ◽

pp. 380-385 ◽

Cited By ~ 52

Author(s):

John C. Hoffsommer ◽

Donald A. Kubose ◽

Donald J. Glover

Keyword(s):

Isotope Effects ◽

Intermediate Formation ◽

Kinetic Isotope Effects ◽

Kinetic Isotope ◽

Hydrolysis Of ◽

Homogeneous Hydrolysis

Studies of the reactions of lamb liver serine hydroxymethylase with L-phenylalanine: kinetic isotope effects upon quinonoid intermediate formation

Biochemistry ◽

10.1021/bi00643a028 ◽

1977 ◽

Vol 16 (24) ◽

pp. 5350-5354 ◽

Cited By ~ 37

Author(s):

Richard J. Ulevitch ◽

Roland G. Kallen

Keyword(s):

Isotope Effects ◽

Intermediate Formation ◽

Kinetic Isotope Effects ◽

Kinetic Isotope

Allene-perfluorocycyclobutanone ene reaction. Kinetic isotope effects

Journal of the American Chemical Society ◽

10.1021/ja00766a049 ◽

1972 ◽

Vol 94 (11) ◽

pp. 3953-3954 ◽

Cited By ~ 13

Author(s):

Sheng-Hong Dai ◽

William R. Dolbier

Keyword(s):

Reaction Kinetic ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Ene Reaction ◽

Kinetic Isotope

Ene reaction mechanisms. 3. Intermolecular and intramolecular kinetic isotope effects (KIE) for some ene reactions of hetero enophiles

The Journal of Organic Chemistry ◽

10.1021/jo00351a006 ◽

1986 ◽

Vol 51 (1) ◽

pp. 37-40 ◽

Cited By ~ 12

Author(s):

Walter Starflinger ◽

Guenter Kresze ◽

Keith Huss

Keyword(s):

Reaction Mechanisms ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Ene Reactions ◽

Ene Reaction ◽

Kinetic Isotope

Kinetic Isotope Effects Provide Experimental Evidence for Proton Tunneling in Methylammonium Lead Triiodide Perovskites

Journal of the American Chemical Society ◽

10.1021/jacs.7b09526 ◽

2017 ◽

Vol 139 (45) ◽

pp. 16359-16364 ◽

Cited By ~ 9

Author(s):

Yan-Fang Chen ◽

Yu-Tang Tsai ◽

Lionel Hirsch ◽

Dario M. Bassani

Keyword(s):

Experimental Evidence ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Proton Tunneling ◽

Kinetic Isotope

ChemInform Abstract: MECHANISM OF THE DIMETHYL MESOXALATE-ALKENE ENE REACTION. DEUTERIUM KINETIC ISOTOPE EFFECTS

Chemischer Informationsdienst ◽

10.1002/chin.198116129 ◽

1981 ◽

Vol 12 (16) ◽

Author(s):

O. JUN. ACHMATOWICZ ◽

J. SZYMONIAK

Keyword(s):

Isotope Effects ◽

Kinetic Isotope Effects ◽

Ene Reaction ◽

Kinetic Isotope

Kinetic Isotope Effects in the Thermal C2−C6Cyclization of Enyne-allenes: Experimental Evidence Supports a Stepwise Mechanism

The Journal of Organic Chemistry ◽

10.1021/jo0504971 ◽

2005 ◽

Vol 70 (12) ◽

pp. 4865-4868 ◽

Cited By ~ 40

Author(s):

Michael Schmittel ◽

Chandrasekhar Vavilala

Keyword(s):

Experimental Evidence ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Stepwise Mechanism ◽

Kinetic Isotope