An Investigation of Zdanovskii’s Rule for Predicting the Water Activity of Multicomponent Aqueous Strong Electrolyte Solutions

2012 ◽  
Vol 57 (9) ◽  
pp. 2589-2602 ◽  
Author(s):  
Darren Rowland ◽  
Peter M. May

1975 ◽  
Vol 53 (10) ◽  
pp. 1410-1413 ◽  
Author(s):  
James Sangster ◽  
Fabio Lenzi

A general thermodynamic expression has been derived for the deviation Δ from Zdanovskii's rule. Conditions have been deduced under which Δ vanishes, and examples given. For nonzero values of Δ it has been shown by means of an example that Δ may be evaluated in some cases by the introduction of empirical assumptions, such as Harned's rule. The use of Zdanovskii's rule in facilitating the integration of the McKay–Perring equation has been discussed briefly.



2008 ◽  
Vol 37 (10) ◽  
pp. 1425-1436 ◽  
Author(s):  
Alexandr A. Zaitsev ◽  
Vladimir N. Afanasiev


2001 ◽  
Vol 40 (22) ◽  
pp. 5021-5028 ◽  
Author(s):  
Manoel J. C. Esteves ◽  
Márcio J. E. de M. Cardoso ◽  
Oswaldo E. Barcia




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