Transition state structures for the hydrolysis of cyclic and acyclic carboxylic acid anhydrides

1983 ◽  
Vol 48 (7) ◽  
pp. 1041-1047 ◽  
Author(s):  
Kenneth R. Davis ◽  
John L. Hogg
Keyword(s):  
Carboxylic Acid ◽  
Transition State ◽  
Acid Anhydrides ◽  
Hydrolysis Of ◽  
Transition State Structures

scholarly journals Transition state structures for the hydrolysis of alpha-D-glucopyranosyl fluoride by retaining and inverting reactions of glycosylases.

1994 ◽  
Vol 269 (51) ◽  
pp. 32306-32312
Author(s):  
Y Tanaka ◽  
W Tao ◽  
J S Blanchard ◽  
E J Hehre
Keyword(s):  
Transition State ◽  
Hydrolysis Of ◽  
Transition State Structures

Isocarbostyrils. II. The Conversion of 2-Methyl-4-acyl-5-nitroisocarbostyrils to 2-Substituted Indole-4-carboxylic Acids

1971 ◽  
Vol 49 (17) ◽  
pp. 2797-2802 ◽  
Author(s):  
D. E. Horning ◽  
G. Lacasse ◽  
J. M. Muchowski
Keyword(s):  
Sulfuric Acid ◽  
Carboxylic Acid ◽  
Carboxylic Acids ◽  
Alkaline Hydrolysis ◽  
Mannich Reaction ◽  
Reductive Cyclization ◽  
Acid Catalyzed ◽  
Acid Anhydrides ◽  
Hydrolysis Of ◽  
Derivatives Of

The sulfuric acid catalyzed acylation of 2-methyl-5-nitroisocarbostyril with carboxylic acid anhydrides gave the corresponding 4-acylated derivatives 3, which underwent reductive cyclization to 2-substituted derivatives of 4-methyl-1,3,4,5-tetrahydropyrrolo[4.3.2.de]isoquinolin-5-one (4). Alkaline hydrolysis of the six-membered lactam in 4 was accompanied by a retro-Mannich reaction to produce 2-substituted indole-4-carboxylic acids in about 40 % overall yield from 3.

Transition-state structures for the hydrolysis of cyclic and acyclic carbonates

1984 ◽  
Vol 49 (17) ◽  
pp. 3161-3166 ◽  
Author(s):  
Ganesa Gopalakrishnan ◽  
John L. Hogg
Keyword(s):  
Transition State ◽  
Hydrolysis Of ◽  
Transition State Structures

Acetylcholinesterase-catalyzed hydrolysis of anilides: acylation reaction dynamics and intrinsic chemical transition-state structures

1987 ◽  
Vol 109 (1) ◽  
pp. 253-257 ◽  
Author(s):  
Paul N. Barlow ◽  
Scott A. Acheson ◽  
Michael L. Swanson ◽  
Daniel M. Quinn
Keyword(s):  
Transition State ◽  
Reaction Dynamics ◽  
Acylation Reaction ◽  
Hydrolysis Of ◽  
Transition State Structures

ChemInform Abstract: Acetylcholinesterase-Catalyzed Hydrolysis of Anilides: Acylation Reaction Dynamics and Intrinsic Chemical Transition-State Structures

ChemInform ◽  
1987 ◽  
Vol 18 (21) ◽  
Author(s):  
P. N. BARLOW ◽  
S. A. ACHESON ◽  
M. L. SWANSON ◽  
D. M. QUINN
Keyword(s):  
Transition State ◽  
Reaction Dynamics ◽  
Acylation Reaction ◽  
Hydrolysis Of ◽  
Transition State Structures

scholarly journals Transition state structures for the hydrolysis of α-D-glucopyranosyl fluoride by retaining and inverting reactions of glycosylases.

1995 ◽  
Vol 270 (10) ◽  
pp. 5686-5686
Author(s):  
Yoshimasa Tanaka ◽  
Wen Tao ◽  
John S. Blanchard ◽  
Edward J. Hehre
Keyword(s):  
Transition State ◽  
Hydrolysis Of ◽  
Transition State Structures
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