Rearrangement and cleavage of the Grignard reagent from 5-(chloromethyl)norbornene

Herein, we describe unprecedented access to all-carbon or heterocyclic seven-membered ring frameworks from 1,8-ene-ynes promoted by inexpensive low-valent titanium(ii) species, readily available from a combination of Ti(OiPr)4 and Grignard reagent.

Download Full-text

Facile intramolecular cyclization of an olefinic grignard reagent

Tetrahedron Letters ◽

10.1016/s0040-4039(00)76054-0 ◽

1966 ◽

Vol 7 (36) ◽

pp. 4297-4301 ◽

Cited By ~ 34

Author(s):

Herman G. Richey ◽

Thomas C. Rees

Keyword(s):

Intramolecular Cyclization ◽

Grignard Reagent

Download Full-text

Process hazard evaluation and exothermic mechanism for the synthesis of n-butylmagnesium bromide Grignard reagent in different solvents

Process Safety and Environmental Protection ◽

10.1016/j.psep.2020.12.041 ◽

2021 ◽

Author(s):

Zhen Cheng ◽

Lei Ni ◽

Junjie Wang ◽

Juncheng Jiang ◽

Hang Yao ◽

...

Keyword(s):

Grignard Reagent ◽

Hazard Evaluation

Download Full-text

ChemInform Abstract: Macrocycles with Sulfide and Amine Binding Sites as Chiral Ligands for Nickel Catalyzed Cross Coupling of a Grignard Reagent with Vinyl Bromide.

Chemischer Informationsdienst ◽

10.1002/chin.198545228 ◽

1985 ◽

Vol 16 (45) ◽

Author(s):

M. LEMAIRE ◽

B. K. VRIESEMA ◽

R. M. KELLOGG

Keyword(s):

Binding Sites ◽

Grignard Reagent ◽

Cross Coupling ◽

Chiral Ligands ◽

Vinyl Bromide

Download Full-text

ChemInform Abstract: STUDIES ON UNSATURATED COMPOUNDS. III. EFFECT OF TEMPERATURE ON THE RELATION BETWEEN NORMAL AND ISOMERIC SUBSTITUTION PRODUCTS DURING THE REACTION OF β,Γ-UNSATURATED HALO DERIVATIVES WITH A GRIGNARD REAGENT

Chemischer Informationsdienst ◽

10.1002/chin.197707097 ◽

1977 ◽

Vol 8 (7) ◽

pp. no-no

Author(s):

G. M. MKRYAN ◽

A. M. MKRTCHYAN ◽

S. M. GASPARYAN

Keyword(s):

Grignard Reagent ◽

Effect Of Temperature ◽

Unsaturated Compounds

Download Full-text

ChemInform Abstract: Reductive Cyclization of Enones by Titanium(IV) Aryloxide and a Grignard Reagent.

ChemInform ◽

10.1002/chin.200207071 ◽

2010 ◽

Vol 33 (7) ◽

pp. no-no

Author(s):

Long Guo Quan ◽

Jin Kun Cha

Keyword(s):

Grignard Reagent ◽

Reductive Cyclization

Download Full-text

Some applications of the methylene di-Grignard reagent for the synthesis of main group IV organometallic compounds

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(85)80101-7 ◽

1985 ◽

Vol 288 (1) ◽

pp. 13-25 ◽

Cited By ~ 33

Author(s):

J.W. Bruin ◽

G. Schat ◽

O.S. Akkerman ◽

F. Bickelhaupt

Keyword(s):

Grignard Reagent ◽

Organometallic Compounds ◽

Main Group ◽

Group Iv

Download Full-text

Diethyl-1-magnesium chloride methanephosphonate, A novel grignard reagent and its use in organic synthesis

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(86)82070-8 ◽

1986 ◽

Vol 316 (1-2) ◽

pp. 13-18 ◽

Cited By ~ 14

Author(s):

P. Coutrot ◽

M. Youssefi-Tabrizi ◽

C. Grison

Keyword(s):

Organic Synthesis ◽

Magnesium Chloride ◽

Grignard Reagent

Download Full-text

The constitution of the Grignard reagent: Part III, Conductivity of some ethylmagnesium compounds

Recueil des Travaux Chimiques des Pays-Bas ◽

10.1002/recl.19640831013 ◽

2010 ◽

Vol 83 (10) ◽

pp. 1096-1102 ◽

Cited By ~ 9

Author(s):

A. D. Vreugdenhil ◽

C. Blomberg

Keyword(s):

Grignard Reagent

Download Full-text