Induced decomposition of di-tert-butyl peroxide using chlorotris(triphenylphosphine)rhodium(I)/hydrogen

1973 ◽  
Vol 38 (15) ◽  
pp. 2722-2723 ◽  
Author(s):  
L. Kim ◽  
K. C. Dewhirst
Keyword(s):  
Tert Butyl ◽  
Butyl Peroxide ◽  
Induced Decomposition

Studies on allylic peroxides. II. Allyl-t-butyl peroxide

1980 ◽  
Vol 58 (5) ◽  
pp. 450-453 ◽  
Author(s):  
R. Hiatt ◽  
V. G. K. Nair
Keyword(s):  
Computer Modelling ◽  
Hydrogen Abstraction ◽  
Radical Addition ◽  
Experimental Results ◽  
Alkoxy Radicals ◽  
Tert Butyl ◽  
Butyl Peroxide ◽  
Induced Decomposition ◽  
Good Agreement

Allyl-tert-butyl peroxide decomposes thermally in toluene with kd = 1013.8 exp (−33200/θ) (s−1). Product studies show the reaction to be a mixture of homolysis and radical-induced decomposition, the latter involving both radical addition to C=C and allyl hydrogen abstraction by alkoxy radicals. Computer modelling of the system gives good agreement with the experimental results and suggests that the overall decomposition is about 50% homolysis.

Fundamental Thermal Hazard Investigation for Tert-Butyl Peroxide Reactor Using DSC and TGA Techniques

2011 ◽  
Vol 21 (1) ◽  
pp. 53-63 ◽  
Author(s):  
Chien-Jung Chen ◽  
Jen-Hao Chi ◽  
Sheng-Hung Wu ◽  
Cheng-Tung Chen ◽  
Hsiu-Fen Tsai
Keyword(s):  
Thermal Hazard ◽  
Tert Butyl ◽  
Butyl Peroxide

Energy partitioning on photolysis of di-tert-butyl peroxide

1971 ◽  
Vol 75 (24) ◽  
pp. 3651-3655 ◽  
Author(s):  
F. H. Dorer ◽  
S. N. Johnson
Keyword(s):  
Energy Partitioning ◽  
Tert Butyl ◽  
Butyl Peroxide

ChemInform Abstract: MANUFACTURE OF DIMETHYL(VINYLETHYNYL)METHYL TERT-BUTYL PEROXIDE

1979 ◽  
Vol 10 (48) ◽  
Author(s):  
M. R. VILENSKAYA ◽  
D. S. KARAMOV ◽  
E. I. SOROKIN ◽  
G. A. PETROVSKAYA ◽  
V. A. PUCHIN
Keyword(s):  
Tert Butyl ◽  
Butyl Peroxide
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