A New Synthesis of Ureas. II. The Reaction of Primary Aliphatic Amines with Carbon Monoxide and Sulfur

1961 ◽  
Vol 26 (9) ◽  
pp. 3306-3308 ◽  
Author(s):  
R. A. FRANZ ◽  
FRED APPLEGATH ◽  
F. V. MORRISS ◽  
FRED BAIOCCHI
Keyword(s):  
Carbon Monoxide ◽  
Aliphatic Amines ◽  
New Synthesis ◽  
Primary Aliphatic Amines

A new synthesis of primary aliphatic amines by N,N-didebenzylation. Synthesis of a pirmenol (CI-845) metabolite

1991 ◽  
Vol 56 (1) ◽  
pp. 457-459 ◽  
Author(s):  
Claude F. Purchase ◽  
O. P. Goel
Keyword(s):  
Aliphatic Amines ◽  
New Synthesis ◽  
Primary Aliphatic Amines

New synthesis of ureas. Reaction of ammonia or aliphatic amines with carbon monoxide in the presence of selenium

1971 ◽  
Vol 93 (23) ◽  
pp. 6344-6344 ◽  
Author(s):  
Noboru Sonoda ◽  
Teruyuki Yasuhara ◽  
Kiyoshi Kondo ◽  
Teruaki Ikeda ◽  
Shigeru Tsutsumi
Keyword(s):  
Carbon Monoxide ◽  
Aliphatic Amines ◽  
New Synthesis

ChemInform Abstract: A New Synthesis of Primary Aliphatic Amines by N,N-Didebenzylation. Synthesis of a Pirmenol (CI-845) Metabolite.

ChemInform ◽  
2010 ◽  
Vol 22 (21) ◽  
pp. no-no
Author(s):  
C. F. II PURCHASE ◽  
O. P. GOEL
Keyword(s):  
Aliphatic Amines ◽  
New Synthesis ◽  
Primary Aliphatic Amines

Exogenous Directing Group Free, Ligand-Enabled gamma-C(sp3)–H Arylation of Free Primary Aliphatic Amines and α-Amino Esters

2019 ◽  
Author(s):  
Yongzheng Ding ◽  
Shuai Fan ◽  
Xiaoxi Chen ◽  
yuzhen gao ◽  
Gang Li
Keyword(s):  
Amino Acids ◽  
Large Scale ◽  
Free Ligand ◽  
Aliphatic Amines ◽  
Rapid Synthesis ◽  
Amino Esters ◽  
Directing Group ◽  
Large Scale Synthesis ◽  
Primary Aliphatic Amines

A Pdᴵᴵ-catalyzed, ligand-enabled gamma-C(sp3)–H arylation of free primary aliphatic amines and amino esters without using an exogenous directing group is reported. This reaction is compatible with unhindered free aliphatic amines, and it is also be applicable to the rapid synthesis of biologically and synthetically valuable unnatural α-amino acids. Large scale synthesis is also feasible using this method.<br>

Pd‐Catalyzed Regio‐ and Stereoselective sp 3 C−H Arylation of Primary Aliphatic Amines: Mechanistic Studies and Synthetic Applications

2021 ◽  
Vol 2021 (7) ◽  
pp. 1136-1145
Author(s):  
Hyeonbin Ha ◽  
Ho Jeong Choi ◽  
Hahyoun Park ◽  
Yunyeong Gwon ◽  
Jiin Lee ◽  
...  
Keyword(s):  
Aliphatic Amines ◽  
Mechanistic Studies ◽  
Primary Aliphatic Amines

Oxidation of primary aliphatic amines with sodium perborate

1989 ◽  
Vol 30 (47) ◽  
pp. 6495-6496 ◽  
Author(s):  
Walter W Zajac ◽  
Michael G Darcy ◽  
Amador P Subong ◽  
John H Buzby
Keyword(s):  
Aliphatic Amines ◽  
Sodium Perborate ◽  
Primary Aliphatic Amines

New Synthesis of N-Acyliminodiacetic Acid by Condensation of Amides with Formaldehyde in the Presence of Carbon Monoxide Catalyzed by Dicobalt Octacarbonyl

1982 ◽  
Vol 12 (14) ◽  
pp. 1111-1114 ◽  
Author(s):  
R. Stern ◽  
D. Reffet ◽  
A. Hirschauer ◽  
D. Commereuc ◽  
Y. Chauvin
Keyword(s):  
Carbon Monoxide ◽  
Dicobalt Octacarbonyl ◽  
New Synthesis

scholarly journals Oxidation of Unactivated Primary Aliphatic Amines Catalyzed by an Electrogenerated 3,4-Azaquinone Species: A Small-Molecule Mimic of Amine Oxidases.

ChemInform ◽  
2003 ◽  
Vol 34 (26) ◽  
Author(s):  
Martine Largeron ◽  
Anne Neudorffer ◽  
Maurice-Bernard Fleury
Keyword(s):  
Small Molecule ◽  
Aliphatic Amines ◽  
Amine Oxidases ◽  
Primary Aliphatic Amines

Synthesis of highly functionalized 4-amino-2-(trifluoromethyl)-1H-pyrroles

Synthesis ◽  
2021 ◽  
Author(s):  
Nilo Zanatta ◽  
Lucimara L Zachow ◽  
Mateus Mittersteiner ◽  
Estefania da Costa Aquino ◽  
Helio G Bonacorso ◽  
...  
Keyword(s):  
Single Crystal ◽  
2D Nmr ◽  
Aliphatic Amines ◽  
X Ray Diffraction ◽  
X Ray ◽  
Reaction Condition ◽  
Primary Aliphatic Amines

In this work, the reactivity of 5-bromo-1,1,1-trifluoro-4-methoxypent-3-en-2-one toward primary aliphatic amines was studied. The reaction was found to be extremely selective to synthesize a series of 1-alkyl-4-aminoalkyl-2-trifluoromethyl-1H-pyrroles (13 examples, at yields up to 90%) and a series of highly functionalized β-enaminones (6 examples, at yields up to 78%), with only the amount of amine and the reaction condition needing to be controlled. The structure of the products was unambiguously determined by single crystal X-ray diffraction and 2D NMR experiments.

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