scholarly journals Recent Developments in the Catalytic, Asymmetric Construction of Pyrroloindolines Bearing All-Carbon Quaternary Stereocenters

2013 ◽  
Vol 78 (24) ◽  
pp. 12314-12320 ◽  
Author(s):  
Lindsay M. Repka ◽  
Sarah E. Reisman
Keyword(s):  
Recent Developments ◽  
Catalytic Asymmetric ◽  
Quaternary Stereocenters

Catalytic asymmetric umpolung reactions of imines via 2-azaallyl anion intermediates

2021 ◽  
Author(s):  
Yaseen Hussain ◽  
Pankaj Chauhan
Keyword(s):  
Review Article ◽  
Recent Developments ◽  
Catalytic Asymmetric

This review article describes all the significant recent developments in catalytic asymmetric umpolung reactions of imines involving a 2-azaallyl anion intermediate.

scholarly journals Highly Enantioselective Construction of Quaternary Stereocenters onβ-Keto Esters by Phase-Transfer Catalytic Asymmetric Alkylation and Michael Reaction

2003 ◽  
Vol 115 (34) ◽  
pp. 4111-4111 ◽  
Author(s):  
Takashi Ooi ◽  
Takashi Miki ◽  
Mika Taniguchi ◽  
Misato Shiraishi ◽  
Mifune Takeuchi ◽  
...  
Keyword(s):  
Michael Reaction ◽  
Phase Transfer ◽  
Asymmetric Alkylation ◽  
Keto Esters ◽  
Catalytic Asymmetric ◽  
Quaternary Stereocenters

scholarly journals Synthesis of Adjacent Quaternary Stereocenters by Catalytic Asymmetric Allylboration

2015 ◽  
Vol 137 (35) ◽  
pp. 11262-11265 ◽  
Author(s):  
Rauful Alam ◽  
Tobias Vollgraff ◽  
Lars Eriksson ◽  
Kálmán J. Szabó
Keyword(s):  
Catalytic Asymmetric ◽  
Quaternary Stereocenters

Catalytic asymmetric synthesis of pyrrolidine derivatives bearing heteroatom-substituted quaternary stereocenters

2018 ◽  
Vol 5 (1) ◽  
pp. 36-40 ◽  
Author(s):  
Zhi-Peng Wang ◽  
Qi Wu ◽  
Jia Jiang ◽  
Zi-Rui Li ◽  
Xiao-Jiao Peng ◽  
...  
Keyword(s):  
Asymmetric Synthesis ◽  
Catalytic Asymmetric Synthesis ◽  
Catalytic Asymmetric ◽  
Quaternary Stereocenters

An enantioselective [3 + 2] cycloaddition of heteroatom-substituted alkenes with α-substituted isocyanoacetates has been developed. Excellent reactivity and enantioselectivity were obtained.

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